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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences


IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

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1865-7117
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Volume 74, Issue 10

Issues

Syntheses, structures, and properties of zinc(II) and copper(II) coordination polymers with imidazole-containing ligands

Long Tang
  • Corresponding author
  • Yan’an University Key Laboratory of New Energy and New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, P.R. China
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ye Guo
  • Yan’an University Key Laboratory of New Energy and New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Shili Xue
  • Yan’an University Key Laboratory of New Energy and New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, P.R. China
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  • De Gruyter OnlineGoogle Scholar
/ Jijiang Wang
  • Corresponding author
  • Yan’an University Key Laboratory of New Energy and New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, P.R. China
  • Email
  • Other articles by this author:
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/ Xiangyang Hou
  • Yan’an University Key Laboratory of New Energy and New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, P.R. China
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  • De Gruyter OnlineGoogle Scholar
/ Xiao Wang
  • Yan’an University Key Laboratory of New Energy and New Functional Materials, Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an 716000, P.R. China
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Published Online: 2019-09-02 | DOI: https://doi.org/10.1515/znb-2019-0107

Abstract

The reactions of Zn(NO3)2 · 6H2O/CuCl2 · 2H2O and 1,4-bis(1-imidazolyl)benzene (bib)/1,4-bis(1-imidazol-1-ylmethyl)benzene (biyb), carried out under hydrothermal conditions, produced two new coordination polymers [Zn(bib)(HCOO)2 · H2O] (1) and [Cu(biyb)Cl2] (2), respectively, which were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analyses, and single-crystal X-ray diffraction. In complex 1, the ZnII centers are bridged by bib ligands to form a chain, where the adjacent chains are condensed by strong intermolecular O–H · · · O hydrogen-bonding and aromatic π-π stacking interactions to generate a 3D supramolecular structure. In 2, the CuII centers are bridged by biyb ligands to form, again, chains through C–H · · · Cl hydrogen bonds, and these adjacent chains with different orientations are joined to generate a 3D supramolecular structure.

Keywords: copper(II); crystal structure; fluorescence properties; imidazolyl-benzene ligands; magnetic behavior; zinc(II)

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About the article

Received: 2019-06-24

Accepted: 2019-08-10

Published Online: 2019-09-02

Published in Print: 2019-10-25


Funding Source: National Natural Science Foundation of China

Award identifier / Grant number: 21573189

Award identifier / Grant number: 21503183

Award identifier / Grant number: 21763028

This work was supported by the National Natural Science Foundation of China (Nos. 21573189, 21503183, and 21763028), the Research Foundation Project of Yan’an University, and the National College Students’ innovation and entrepreneurship training program (D2017009).


Citation Information: Zeitschrift für Naturforschung B, Volume 74, Issue 10, Pages 739–744, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2019-0107.

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