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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

IMPACT FACTOR 2018: 0.961

CiteScore 2018: 0.91

SCImago Journal Rank (SJR) 2018: 0.263
Source Normalized Impact per Paper (SNIP) 2018: 0.505

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Volume 74, Issue 5


A Mn(II) complex with an amide-containing ligand: synthesis, structural characterization, and magnetic properties

Xiao-Hong Zhu / Ding-Yun Jiang / Xiao-Chun Cheng / Deng-Hao Li / Wei-Gang Du
Published Online: 2019-04-16 | DOI: https://doi.org/10.1515/znb-2018-0270


A new Mn(II) complex [Mn2(L)(H2O)3] · (H2O)4.8 (1) was synthesized via the hydrothermal reaction of MnCl2 · 4H2O with N4,N4′-di(5-isophthalyl)biphenyl-4,4′-dicarboxamide (H4L). Complex 1 is characterized by single-crystal and powder X-ray diffraction, infraredspectroscopy, and elemental and thermogravimetric analyses. 1 exhibits a uninodal 5-connected 3D bnn framework structure with (46.64) topology. The magnetic properties of 1 were investigated.

Keywords: amide; crystal structure; magnetism; manganese(II)


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About the article

Received: 2018-12-02

Accepted: 2019-03-25

Published Online: 2019-04-16

Published in Print: 2019-05-27

Funding Source: Natural Science Foundation for Universities in Jiangsu Province

Award identifier / Grant number: 16KJB150005

Funding Source: Huaiyin Institute of Technology

Award identifier / Grant number: 15HGZ006 and 491713325

The authors gratefully acknowledge the Natural Science Foundation for Universities in Jiangsu Province (16KJB150005) and Huaiyin Institute of Technology (15HGZ006 and 491713325) for their financial support in this work.

Citation Information: Zeitschrift für Naturforschung B, Volume 74, Issue 5, Pages 409–414, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0270.

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