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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Volume 72, Issue 3 (Mar 2017)

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Synthesis, crystal structure and magnetic properties of the complex [C(NH2)3]2[Mn(N3)4] with a polynuclear azido-bridged chain anion

Kun Qian
  • Corresponding author
  • College of Pharmacy, Jiangxi University of Traditional Chinese Medicine, Nanchang, 330004, P.R. China
  • Email:
/ Yan-hong Yu
  • College of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang, 330013, P.R. China
/ Yao-Hui Ye
  • College of Pharmacy, Jiangxi University of Traditional Chinese Medicine, Nanchang, 330004, P.R. China
/ Hao Fan
  • College of Pharmacy, Jiangxi University of Traditional Chinese Medicine, Nanchang, 330004, P.R. China
Published Online: 2017-02-23 | DOI: https://doi.org/10.1515/znb-2016-0221

Abstract

A new complex [C(NH2)3]2[Mn(N3)4], in which MnII cations are alternatively bridged by double EE azide-bridges and the [Mn(N3)4]n2− chains are separated by guanidinium cation bilayers, has been synthesized and characterized by single crystal X-ray diffraction, infrared (IR) spectroscopy, elemental analyses, and magnetic measurements. Magnetic susceptibility data indicate antiferromagnetic interaction among the MnII ions.

Keywords: antiferromagnetism; azido-bridged couple; coordination polymer

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About the article

Received: 2016-09-29

Accepted: 2016-11-18

Published Online: 2017-02-23

Published in Print: 2017-03-01



Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2016-0221. Export Citation

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