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Get Access to Full TextA new complex [C(NH2)3]2[Mn(N3)4], in which MnII cations are alternatively bridged by double EE azide-bridges and the [Mn(N3)4]n2− chains are separated by guanidinium cation bilayers, has been synthesized and characterized by single crystal X-ray diffraction, infrared (IR) spectroscopy, elemental analyses, and magnetic measurements. Magnetic susceptibility data indicate antiferromagnetic interaction among the MnII ions.
Keywords: antiferromagnetism; azido-bridged couple; coordination polymer
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Received: 2016-09-29
Accepted: 2016-11-18
Published Online: 2017-02-23
Published in Print: 2017-03-01
Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2016-0221.
©2017 Walter de Gruyter GmbH, Berlin/Boston.
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