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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

SCImago Journal Rank (SJR) 2016: 0.237
Source Normalized Impact per Paper (SNIP) 2016: 0.332

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1865-7117
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Volume 72, Issue 3 (Mar 2017)

Issues

Synthesis, crystal structure and Raman spectrum of Ba7[BO3]3Br(O1.33F1.33)

Olaf Reckeweg
  • Corresponding author
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA, Fax:+1-607-255-4137
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Armin Schulz
  • Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany
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  • De Gruyter OnlineGoogle Scholar
/ Francis J. DiSalvo
  • Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA
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Published Online: 2017-01-20 | DOI: https://doi.org/10.1515/znb-2016-0243

Abstract

In addition to amorphous material and Ba7[BO3]4−x F2−3x , air and moisture sensitive single crystals of Ba7[BO3]3Br(O1.33F1.33) were formed from H3BO3, Ba(OH)2, BaF2 and BaBr2·2 H2O in alumina crucibles open to the atmosphere at 1300 K for 13 h. Ba7[BO3]3Br(O1.33F1.33) crystallizes in the hexagonal space group P63mc (no. 186, Z=2) with the lattice parameters a=1118.1(2) and c=723.93(13) pm. The Raman spectrum of the title compounds was also acquired and is compared to literature data.

Keywords: barium; bromide; fluoride; orthoborate; oxide; Raman spectrum

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About the article

aPrivate address: Krönerstr. 10, 31737 Rinteln, Germany


Received: 2016-10-31

Accepted: 2016-11-23

Published Online: 2017-01-20

Published in Print: 2017-03-01


Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2016-0243.

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