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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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Volume 73, Issue 8

Issues

Oxidative coupling of cycloalkanones with 3-(pyridin-2-yl)-1,2,4-triazinone coordinated to Pd(II)

Mustafa M. El-Abadelah / Firas F. Awwadi / Hamdallah A. Hodali / Rasha S. Rawajfeh / Monther S. Zreid / Wolfgang Voelter
  • Corresponding author
  • Interfakultäres Institut für Biochemie, Universität Tübingen, Hoppe-Seyler-Straße 4, 72076 Tübingen, Germany
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Published Online: 2018-07-13 | DOI: https://doi.org/10.1515/znb-2018-0077

Abstract

Dichloro[3-(pyridin-2-yl)-1,2,4-triazinone]Pd(II) undergoes oxidative C–C coupling reaction with cyclopentanone and cyclohexanone at 110°C to yield the respective Pd complexes, chloro[1-(4-chlorophenyl)-5-(2-hydroxycyclopent-1-enyl)-3-(pyridin-2-yl)-1,2,4-triazin-6(1H)-one]palladium(II) (3) and chloro[1-(4-chlorophenyl)-5-(2-hydroxycyclohex-1-enyl)-3-(pyridin-2-yl)-1,2,4-triazin-6(1H)-one]palladium(II) (4). The structures of both complexes are supported by spectral data and confirmed by single-crystal X-ray crystallography. The molecules 3 and 4 stack to form tunnel structures, whilst the geometry around the palladium ion is square planar.

This article offers supplementary material which is provided at the end of the article.

Keywords: cyclohexanone; cyclopentanone; oxidative C–C coupling; Pd-pyridyl-1,2,4-triazinone; X-ray crystal structures

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About the article

Received: 2018-04-19

Accepted: 2018-06-13

Published Online: 2018-07-13

Published in Print: 2018-08-28


Citation Information: Zeitschrift für Naturforschung B, Volume 73, Issue 8, Pages 583–587, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0077.

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