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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Cationic tri(ferrocenecarbonitrile)silver(I)

Frank Strehler
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
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/ Tobias Rüffer
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
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/ Julian Noll
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
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/ Dieter Schaarschmidt
  • Universität Hamburg, Institut für Anorganische Chemie, Martin-Luther-King-Platz 6, 20146 Hamburg, Germany
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/ Alexander Hildebrandt
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany
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/ Heinrich Lang
  • Corresponding author
  • Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany, Tel. +49 (0)371 531 21210, Fax +49 (0)371 531 21219
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Published Online: 2018-08-30 | DOI: https://doi.org/10.1515/znb-2018-0090

Abstract

The synthesis of the tri-coordinated ferrocenecarbonitrile silver(I) complex [Ag(N≡CFc)3]OTf (3) is reported. Its electrochemical behavior shows that the three ferrocenyl units are oxidized in a very close potential range. In addition, the molecular structure of 3 in the solid state is discussed, showing that silver(I) is exclusively coordinated by three ferrocenecarbonitrile molecules.

Graphical Abstract

This article offers supplementary material which is provided at the end of the article.

Keywords: electrochemistry; ferrocenecarbonitrile; silver; solid state structure; trigonal coordination

Dedicated to: Professor Bernt Krebs on the occasion of his 80th birthday.

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About the article

Received: 2018-05-16

Accepted: 2018-08-08

Published Online: 2018-08-30


Citation Information: Zeitschrift für Naturforschung B, 20180090, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0090.

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