Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

Online
ISSN
1865-7117
See all formats and pricing
More options …
Ahead of print

Issues

7-Methyl-6-furylpurine forms dinuclear metal complexes with N3,N9 coordination

Indranil Sinha
  • Westfälische Wilhelms-Universität Münster, Institut für Anorganische und Analytische Chemie, Corrensstraße 28/30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Lukas Heller
  • Westfälische Wilhelms-Universität Münster, Institut für Anorganische und Analytische Chemie, Corrensstraße 28/30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jutta Kösters
  • Westfälische Wilhelms-Universität Münster, Institut für Anorganische und Analytische Chemie, Corrensstraße 28/30, 48149 Münster, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jens Müller
  • Corresponding author
  • Westfälische Wilhelms-Universität Münster, Institut für Anorganische und Analytische Chemie, Corrensstraße 28/30, 48149 Münster, Germany, Phone: +49 251 83 36006
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2018-08-11 | DOI: https://doi.org/10.1515/znb-2018-0110

Abstract

Two dinuclear metal complexes bearing the purine derivative 7-methyl-6-furylpurine (1b) as a ligand are reported. In [Ag2(1b)2(DMSO)2](ClO4)2·DMSO and [Cu2(1b)2(NO3)2], two bridging purine derivatives coordinate the two metal ions via their N3 and N9 positions. In the silver(I) complex, the coordination environment of each metal ion is completed by a DMSO ligand, whereas an additional nitrato ligand coordinates to each copper(I) ion. The intramolecular Ag···Ag distance of 3.1069(5) Å is in agreement with the presence of a weak argentophilic interaction, whereas the Cu···Cu distance of 2.9382(4) Å is too long to be indicative of a cuprophilic interaction. The compounds represent the first examples of dinuclear complexes comprising two N3,N9-bridging purine derivatives without any additional bridging ligand.

Graphical Abstract

Keywords: copper; metallophilic interaction; purine; silver

Dedicated to: Professor Bernt Krebs on the occasion of his 80th birthday.

References

  • [1]

    B. Lippert, Prog. Inorg. Chem. 1989, 37, 1.Google Scholar

  • [2]

    B. Lippert, Coord. Chem. Rev. 2000, 200–202, 487.Google Scholar

  • [3]

    J. Müller, Metallomics 2010, 2, 318.CrossrefGoogle Scholar

  • [4]

    H. Sigel, Chem. Soc. Rev. 1993, 22, 255.CrossrefGoogle Scholar

  • [5]

    R. M. Izatt, J. J. Christensen, J. H. Rytting, Chem. Rev. 1971, 71, 439.CrossrefGoogle Scholar

  • [6]

    B. Lippert, D. Gupta, Dalton Trans. 2009, 4619.Google Scholar

  • [7]

    A. Collado, M. Gómez-Gallego, M. A. Sierra, Eur. J. Org. Chem. 2018, 2018, 1617.CrossrefGoogle Scholar

  • [8]

    D. Brackemeyer, A. Hervé, C. Schulte to Brinke, M. C. Jahnke, F. E. Hahn, J. Am. Chem. Soc. 2014, 136, 7841.CrossrefGoogle Scholar

  • [9]

    I. Sinha, A. Hepp, B. Schirmer, J. Kösters, J. Neugebauer, J. Müller, Inorg. Chem. 2015, 54, 4183.CrossrefGoogle Scholar

  • [10]

    M. A. Galindo, A. Houlton, Inorg. Chim. Acta 2009, 362, 625.CrossrefGoogle Scholar

  • [11]

    B. Mohapatra, Pratibha, S. Verma, Chem. Commun. 2017, 53, 4748.CrossrefGoogle Scholar

  • [12]

    S. Verma, A. K. Mishra, J. Kumar, Acc. Chem. Res. 2010, 43, 79.CrossrefGoogle Scholar

  • [13]

    S. Sivakova, S. J. Rowan, Chem. Soc. Rev. 2005, 34, 9.CrossrefGoogle Scholar

  • [14]

    F. Zamora, M. P. Amo-Ochoa, P. J. Sanz Miguel, O. Castillo, Inorg. Chim. Acta 2009, 362, 691.CrossrefGoogle Scholar

  • [15]

    L. L. G. Al-Mahamad, O. El-Zubir, D. G. Smith, B. R. Horrocks, A. Houlton, Nat. Commun. 2017, 8, 720.CrossrefGoogle Scholar

  • [16]

    D. Dutta, N. Nagapradeep, H. Zhu, M. Forsyth, S. Verma, A. J. Bhattacharyya, Sci. Rep. 2016, 6, 24499.CrossrefGoogle Scholar

  • [17]

    B. Lippert, P. J. Sanz Miguel, Acc. Chem. Res. 2016, 49, 1537.CrossrefGoogle Scholar

  • [18]

    R. B. Martin in Metal Ions in Biological Systems, Vol. 32 (Eds.: H. Sigel, A. Sigel), Marcel Dekker, Inc., New York, 1996, p. 61.Google Scholar

  • [19]

    S. Mandal, C. Wang, R. K. Prajapati, J. Kösters, S. Verma, L. Chi, J. Müller, Inorg. Chem. 2016, 55, 7041.CrossrefGoogle Scholar

  • [20]

    I. Sinha, J. Kösters, A. Hepp, J. Müller, Dalton Trans. 2013, 42, 16080.CrossrefGoogle Scholar

  • [21]

    I. E. Markó, P. R. Giles, M. Tsukazaki, S. M. Brown, C. J. Urch, Science 1996, 274, 2044.CrossrefGoogle Scholar

  • [22]

    C. Radunsky, J. Kösters, M. C. Letzel, S. Yogendra, C. Schwickert, S. Manck, B. Sarkar, R. Pöttgen, J. J. Weigand, J. Neugebauer, J. Müller, Eur. J. Inorg. Chem. 2015, 2015, 4006.Google Scholar

  • [23]

    T. Suzuki, H. Yamaguchi, A. Hashimoto, K. Nozaki, M. Doi, N. Inazumi, N. Ikeda, S. Kawata, M. Kojima, H. D. Takagi, Inorg. Chem. 2011, 50, 3981.CrossrefGoogle Scholar

  • [24]

    A. Bondi, J. Phys. Chem. 1964, 68, 441.CrossrefGoogle Scholar

  • [25]

    H. Schmidbaur, A. Schier, Angew. Chem. Int. Ed. 2015, 54, 746.CrossrefGoogle Scholar

  • [26]

    H. Tatewaki, Y. Hatano, T. Naka, T. Noro, S. Yamamoto, Bull. Chem. Soc. Jpn. 2010, 83, 1203.CrossrefGoogle Scholar

  • [27]

    G. J. Kleywegt, W. G. R. Wiesmeijer, G. J. Van Driel, W. L. Driessen, J. Reedijk, J. H. Noordik, J. Chem. Soc., Dalton Trans. 1985, 2177.Google Scholar

  • [28]

    A. Terzis, A. L. Beauchamp, R. Rivest, Inorg. Chem. 1973, 12, 1166.CrossrefGoogle Scholar

  • [29]

    E. Sletten, Acta Crystallogr. 1969, B25, 1480.Google Scholar

  • [30]

    A. Klanicová, Z. Trávníček, J. Vančo, I. Popa, Z. Šindelár, Polyhedron, 2010, 29, 2582.CrossrefGoogle Scholar

  • [31]

    P. de Meester, A. C. Skapski, J. Chem. Soc. A 1971, 2167.Google Scholar

  • [32]

    J. Thomas-Gipson, G. Beobide, O. Castillo, J. Cepeda, A. Luque, S. Pérez-Yáñez, A. T. Aguayo, P. Román, CrystEngComm 2011, 13, 3301.CrossrefGoogle Scholar

  • [33]

    J. Cepeda, O. Castillo, J. P. García-Terán, A. Luque, S. Pérez-Yáñez, P. Román, Eur. J. Inorg. Chem. 2009, 2009, 2344.CrossrefGoogle Scholar

  • [34]

    A. Klanicová, Z. Trávníček, I. Popa, M. Čajan, K. Doležal, Polyhedron 2006, 25, 1421.CrossrefGoogle Scholar

  • [35]

    J. M. González-Pérez, C. Alarcón-Payer, A. Castiñeiras, T. Pivetta, L. Lezama, D. Choquesillo-Lazarte, G. Crisponi, J. Niclós-Gutiérrez, Inorg. Chem. 2006, 45, 877.CrossrefGoogle Scholar

  • [36]

    J. Thomas-Gipson, G. Beobide, O. Castillo, M. Fröba, F. Hoffmann, A. Luque, S. Pérez-Yáñez, P. Román, Cryst. Growth Des. 2014, 14, 4019.CrossrefGoogle Scholar

  • [37]

    H. Q. Yuan, K. Aoki, I. Fujisawa, Inorg. Chim. Acta 2009, 362, 975.CrossrefGoogle Scholar

  • [38]

    P. S. Nugent, V. L. Rhodus, T. Pham, K. Forrest, L. Wojtas, B. Space, M. J. Zaworotko, J. Am. Chem. Soc. 2013, 135, 10950.CrossrefGoogle Scholar

  • [39]

    R. Pérez-Aguirre, G. Beobide, O. Castillo, I. de Pedro, S. Pérez-Yáñez, Inorg. Chim. Acta 2016, 452, 222.CrossrefGoogle Scholar

  • [40]

    J. Thomas-Gipson, R. Pérez-Aguirre, G. Beobide, O. Castillo, A. Luque, S. Pérez-Yáñez, P. Román, Cryst. Growth Des. 2015, 15, 975.CrossrefGoogle Scholar

  • [41]

    S. R. Sushrutha, R. Hota, S. Natarajan, Eur. J. Inorg. Chem. 2016, 2016, 2962.CrossrefGoogle Scholar

  • [42]

    S. Zhang, H. He, F. Sun, N. Zhao, J. Du, Q. Pan, G. Zhu, Inorg. Chem. Commun. 2017, 79, 55.CrossrefGoogle Scholar

  • [43]

    G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.Google Scholar

About the article

Received: 2018-06-14

Accepted: 2018-07-18

Published Online: 2018-08-11


Citation Information: Zeitschrift für Naturforschung B, 20180110, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0110.

Export Citation

©2018 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Comments (0)

Please log in or register to comment.
Log in