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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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1865-7117
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A new modification of [Ag4Br4(PPh3)4]: synthesis, structure and properties

Xintong Han
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Shanshan Mao
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Chuang Li
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Kesheng Shen
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Xinkui Shi
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Guozhen Huang
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
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  • De Gruyter OnlineGoogle Scholar
/ Huilu Wu
  • Corresponding author
  • School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P.R. China
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Published Online: 2018-08-20 | DOI: https://doi.org/10.1515/znb-2018-0113

Abstract

A new modification of the homometallic silver(I) cluster [Ag4Br4(PPh3)4] has been prepared and characterized by elemental analysis, UV/Vis and IR spectroscopy, and X-ray crystallography. The tetramer shows a polycyclic structure with a chair conformation. The bromine atoms adopt μ2- and μ3-bridging modes. The shortest Ag–Ag distance in the cluster is 3.159(2) Å, which indicates significant Ag–Ag interactions. A supramolecular structure is arranged by hydrogen bonds (C–H···Br). Cyclic voltammograms of the cluster indicate a quasi-reversible Ag+/Ag couple. The fluorescence properties of the ligand and the Ag(I) cluster were studied in the solid state. The emission peaks of the Ag(I) cluster are attributed to ligand-centered luminescence.

Graphical Abstract

Keywords: cluster; crystal structure; electrochemical study; fluorescence; silver

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About the article

Received: 2018-06-20

Accepted: 2018-07-21

Published Online: 2018-08-20


Citation Information: Zeitschrift für Naturforschung B, 20180113, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0113.

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