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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Synthesis, characterization, and electrochemical study of a mononuclear Cu(II) complex with a 4-acyl pyrazolone ligand

Kiran Nakum
  • Faculty of Science, Department of Chemistry, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
  • Other articles by this author:
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/ Rajendrasinh N. Jadeja
  • Corresponding author
  • Faculty of Science, Department of Chemistry, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
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Published Online: 2018-08-20 | DOI: https://doi.org/10.1515/znb-2018-0117

Abstract

1-(2-Chlorophenyl)-3-methyl-4-propionyl-1H-pyrazol-5(4H)-one was synthesized and characterized by Fourier transform infrared (FT-IR) spectroscopy, 1H nuclear magnetic resonance, and single-crystal X-ray analysis. Its Cu(II) complex was prepared and characterized by FT-IR, thermo gravimetric analysis-differential thermal analysis, ultraviolet-visible spectroscopy, cyclic voltammetry, and single-crystal X-ray structure determination. On the basis of analytical and spectroscopic techniques, a distorted square planar geometry of the complex has been found.

Graphical Abstract

Keywords: crystal structure; Cu(II) complex; electrochemical study; pyrazolone

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About the article

Received: 2018-06-07

Accepted: 2018-07-29

Published Online: 2018-08-20


Citation Information: Zeitschrift für Naturforschung B, 20180117, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0117.

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