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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}

Marit Gudenschwager
  • Institut für Anorganische Chemie, Universität zu Köln, Greinstraße 6, 50939 Köln, Germany
  • Other articles by this author:
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/ Jens Christoffers
  • Institut für Chemie, Carl von Ossietzky-Universität Oldenburg, Carl von Ossietzky-Straße 9–11, 29129 Oldenburg, Germany
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/ Mathias S. Wickleder
  • Corresponding author
  • Institut für Anorganische Chemie, Universität zu Köln, Greinstraße 6, 50939 Köln, Germany
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Published Online: 2018-12-10 | DOI: https://doi.org/10.1515/znb-2018-0152

Abstract

The reaction of Ni(OH)2 and methanetrisulfonic acid trihydrate CH(SO3H)3·3H2O (H3MTA·3H2O) in N-methyl-pyrrolidone (NMP) leads to the trinuclear complex {Ni3[MTA]2(NMP)8} (triclinic, P1̅, Z=1, a=946.25(3), b=1073.24(3), c=1518.27(4) pm, α=72.193(2), β=87.398(2), γ=89.389(2)°, V=1466.49(7)×106 pm3). The structural features of the methanetrisulfonate anions are tripodal as well as chelating coordination of the Ni2+ ions. The thermal analysis has shown that the compound is first losing NMP molecules and that the solvent-free methanetrisulfonate finally decomposes yielding Ni3S2.

Keywords: crystal structure; methanesulfonic acids; methanetrisulfonate; nickel complex; thermal analysis

Dediacted to: Professor Wolfgang Bensch on the occasion of his 65th birthday.

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About the article

Received: 2018-07-24

Accepted: 2018-10-20

Published Online: 2018-12-10


Citation Information: Zeitschrift für Naturforschung B, 20180152, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0152.

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