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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand

Zahra Mardani
  • Corresponding author
  • Inorganic Chemistry Department, Faculty of Chemistry, Urmia University, 57561-51818 Urmia, I.R. Iran
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Reza Kazemshoar-Duzduzani
  • Inorganic Chemistry Department, Faculty of Chemistry, Urmia University, 57561-51818 Urmia, I.R. Iran
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Keyvan Moeini / Majid Darroudi / Cameron Carpenter-Warren / Alexandra M.Z. Slawin / J. Derek Woollins
Published Online: 2018-11-09 | DOI: https://doi.org/10.1515/znb-2018-0158

Abstract

A cadmium–mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O–H···I hydrogen bonds, and these interactions lead to the formation of an R44(22) motif.

Keywords: β-amino alcohol; Cd/Hg mixed-metal complex; diastereomer; X-ray crystal structure

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About the article

Received: 2018-07-22

Accepted: 2018-08-25

Published Online: 2018-11-09


Citation Information: Zeitschrift für Naturforschung B, 20180158, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0158.

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