Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

Online
ISSN
1865-7117
See all formats and pricing
More options …
Ahead of print

Issues

Crystal and molecular structure of trans-[RhCl(CO)(PtBu2Ph)2]

Peter Mayer
  • Department Chemie der Ludwig-Maximilians-Universität, Butenandtstraße 5-13, München 81377, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Hans-Christian Böttcher
  • Corresponding author
  • Department Chemie der Ludwig-Maximilians-Universität, Butenandtstraße 5-13, München 81377, Germany
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2018-10-04 | DOI: https://doi.org/10.1515/znb-2018-0163

Abstract

Treatment of THF solutions containing the rhodium(II) complex trans-[RhCl2(PtBu2Ph)2] (1) with [Fe2(CO)9] in the same solvent resulted in the formation of the Vaska-type complex trans-[RhCl(CO)(PtBu2Ph)2] (2) in high yield. The title complex 2 was obtained as pale yellow crystals, characterized by NMR and IR spectroscopy, as well as by microanalyses. Additionally, the molecular structure of 2 has been established by X-ray crystallography. As often reported for similar constituted compounds, the chlorido and carbonyl ligands in crystals of 2 are strongly disordered.

Keywords: crystal structure; metal carbonyls; phosphane complex; rhodium(I)

Dedicated to: Professor Ingo-Peter Lorenz on the occasion of his 75th birthday.

References

  • [1]

    H.-C. Böttcher, P. Klüfers, T. Mies, P. Mayer, Z. Anorg. Allg. Chem. (in press) doi: 10.1002/zaac.201800297.Google Scholar

  • [2]

    B. E. Mann, C. Masters, B. L. Shaw, J. Chem. Soc. A 1971, 1104.CrossrefGoogle Scholar

  • [3]

    G. M. Sheldrick, Acta Crystallogr. 2015, A71, 3.Google Scholar

  • [4]

    G. M. Sheldrick, Acta Crystallogr. 2015, C71, 3.Google Scholar

  • [5]

    F. A. Cotton, B. G. DeBoer, M. D. LaPrade, J. R. Pipal, D. A. Ucko, Acta Crystallogr. 1971, B27, 1664.Google Scholar

  • [6]

    F. A. Cotton, J. M. Troup, J. Am. Chem. Soc. 1974, 96, 3438.CrossrefGoogle Scholar

  • [7]

    C. M. DiMeglio, L. A. Luck, C. D. Rithner, A. L. Rheingold, W. L. Elcesser, J. L. Hubbard, C. H. Bushweller, J. Phys. Chem. 1990, 94, 6255.CrossrefGoogle Scholar

  • [8]

    C. H. Bushweller, S. Hoogasian, A. D. English, J. S. Miller, M. Z. Lourandos, Inorg. Chem. 1981, 20, 3448.CrossrefGoogle Scholar

  • [9]

    H.-C. Böttcher, M. Junk, P. Mayer, W. Beck, Eur. J. Inorg. Chem. 2015, 3323.Google Scholar

  • [10]

    K. R. Dunbar, S. C. Haefner, Inorg. Chem. 1992, 31, 3676.CrossrefGoogle Scholar

  • [11]

    L. Dahlenburg, A. Yardimcioglu, J. Organomet. Chem. 1985, 291, 371 and references cited therein.CrossrefGoogle Scholar

  • [12]

    D. Capitani, P. Mura, Inorg. Chim. Acta 1997, 258, 169.CrossrefGoogle Scholar

  • [13]

    H.-C. Böttcher, M. Graf, P. Mayer, K. Sünkel, Z. Anorg. Allg. Chem. 2008, 634, 1241.CrossrefGoogle Scholar

About the article

Received: 2018-08-01

Accepted: 2018-08-26

Published Online: 2018-10-04


Citation Information: Zeitschrift für Naturforschung B, 20180163, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-2018-0163.

Export Citation

©2018 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Comments (0)

Please log in or register to comment.
Log in