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Zeitschrift für Naturforschung C

A Journal of Biosciences

Editor-in-Chief: Seibel, Jürgen

Editorial Board: Aigner , Achim / Boland, Wilhelm / Bornscheuer, Uwe / Hoffmann, Klaus


IMPACT FACTOR 2018: 1.000

CiteScore 2018: 0.99

SCImago Journal Rank (SJR) 2018: 0.246
Source Normalized Impact per Paper (SNIP) 2018: 0.437

Online
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1865-7125
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Volume 49, Issue 9-10

Issues

Phylogeny and Biotransformation. Part 5*: Biotransformation of Isopinocampheol

Wolf-Rainer Abraham
  • GBF - Gesellschaft für Biotechnologische Forschung mbH. Abteilung Mikrobiologie, Mascheroder Weg 1, D-38124 Braunschweig, Bundesrepublik Deutschland
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znc-1994-9-1004

Abstract

Biotransformation of isopinocampheol with 100 bacterial and fungal strains yielded 1-, 2-, 4-, 5-, 7-, 8 - and 9-hydroxy-isopinocampheol besides three rearranged monoterpenes, one of them bearing the novel isocarane skeleton. A pronounced enantioselectivity between (+)- and (-)-isopinocampheol was observed. The phylogenetic position of the individual strains could be seen in their ability to form the products from (+)-isopinocampheol. The formation of 1,3-dihydroxypinane is a domain of bacteria, while 3,5- or 3,7-dihydroxypinane was mainly formed by fungi, especially those of the phylum Zygomycotina. The activity of Basidiomycotina towards oxidation of isopinocampheol was rather low. Such informations can be used in a more effective selection of strains for screening.

Keywords: Biotransformation; Phylogeny; Isopinocampheol; Enantioselectivity; Microbial Hydroxylation

About the article

Received: 1994-03-11

Published Online: 2014-06-02

Published in Print: 1994-10-01


Citation Information: Zeitschrift für Naturforschung C, Volume 49, Issue 9-10, Pages 553–560, ISSN (Online) 1865-7125, ISSN (Print) 0939-5075, DOI: https://doi.org/10.1515/znc-1994-9-1004.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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