Zeitschrift für Physikalische Chemie
International journal of research in physical chemistry and chemical physics
Ed. by Rademann, Klaus
IMPACT FACTOR 2015: 1.183
SCImago Journal Rank (SJR) 2015: 0.491
Source Normalized Impact per Paper (SNIP) 2015: 0.520
Impact per Publication (IPP) 2015: 1.133
Homogeneous Ice Nucleation in Water and Aqueous Solutions
Citation Information: Zeitschrift für Physikalische Chemie. Volume 218, Issue 11/2004, Pages 1231–1258, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.218.11.1231.50812, September 2009
- Published Online:
This review provides an introduction to ice nucleation processes in supercooled water and aqueous solutions. Concepts for experimental techniques suitable to study homogeneous ice nucleation are addressed, in particular differential scanning calorimetry of inverse emulsions. Ice nucleation data from aqueous solutions have been analyzed using two approaches, and the interrelations between those are examined. It is argued that the ice nucleation process is driven entirely by thermodynamic quantities and how this can be understood in the context of three proposed theories for supercooled liquid water. Ice nucleation data for pure water droplets surrounded by a gas have been compiled and evaluated; within experimental uncertainty neither a volume dependent nucleation process nor a surface dependent nucleation process is convincingly supported by the analysis. Finally, open questions in the area of supercooled aqueous solutions and ice nucleation are discussed.
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