Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus


IMPACT FACTOR 2018: 0.975
5-year IMPACT FACTOR: 1.021

CiteScore 2018: 1.20

SCImago Journal Rank (SJR) 2018: 0.327
Source Normalized Impact per Paper (SNIP) 2018: 0.391

Online
ISSN
2196-7156
See all formats and pricing
More options …
Volume 218, Issue 7

Issues

Comparison of the Macroscopic Molecular Properties in Understanding the Structural Aspects of Mixed Aquo–Organic Binary Mixtures

Dilip Kumar Kuila / S. C. Lahiri
Published Online: 2008-05-26 | DOI: https://doi.org/10.1524/zpch.218.7.803.35726

Abstract

Understanding the structural aspects of aquo + organic mixtures and finding out a suitable physico-chemical parameter as a structural probe is of great importance from a theoretical and experimental point of view.

Attempts have been made to derive useful relations regarding the structure of aquo + organic mixtures [ethylene glycol + water, glycerol + water, dioxane + water, acetone + water and acetonitrile + water mixtures] of widely divergent characteristics based on different macroscopic molecular properties: (i) excess thermodynamic properties of mixing, (ii) excess dielectric constants, (iii) excess polarizability volumes, (iii) correlation factor ‘g’, (v) ultrasonic sound absorption, (vi) basicity or other suitable expressions. The properties give valuable details regarding the structure of aquo + organic mixtures.

Macroscopic molecular properties provide a summary of all interaction energies over a long time, but finer structural details may be available from microscopic properties (using relaxation techniques etc.).

A comparison of the macroscopic and microscopic methods for the determination of structural aspects of solvent systems is presented.

About the article

Published Online: 2008-05-26

Published in Print: 2004-07-01


Citation Information: Zeitschrift für Physikalische Chemie, Volume 218, Issue 7, Pages 803–828, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.218.7.803.35726.

Export Citation

© 2004 Oldenbourg Wissenschaftsverlag GmbH.Get Permission

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Elliot L. Bennett, Chaoyun Song, Yi Huang, and Jianliang Xiao
Journal of Molecular Liquids, 2019, Page 111571
[3]
Xuehong Zhao, Shu’ni Li, Quanguo Zhai, Yucheng Jiang, and Mancheng Hu
Journal of Chemical & Engineering Data, 2015, Volume 60, Number 3, Page 697
[4]
[5]
Rex W. Watkins, Luke D. Lavis, Vanessa M. Kung, Georgyi V. Los, and Ronald T. Raines
Organic & Biomolecular Chemistry, 2009, Volume 7, Number 19, Page 3969
[6]
Bjørn Maribo-Mogensen, Georgios M. Kontogeorgis, and Kaj Thomsen
The Journal of Physical Chemistry B, 2013, Volume 117, Number 12, Page 3389
[9]
Yizhak Marcus
Journal of Physical Organic Chemistry, 2012, Volume 25, Number 12, Page 1072
[12]
N. Ouerfelli, O. Iulian, R. Besbes, Z. Barhoumi, and N. Amdouni
Physics and Chemistry of Liquids, 2012, Volume 50, Number 1, Page 54

Comments (0)

Please log in or register to comment.
Log in