Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus

IMPACT FACTOR 2018: 0.975
5-year IMPACT FACTOR: 1.021

CiteScore 2018: 1.20

SCImago Journal Rank (SJR) 2018: 0.327
Source Normalized Impact per Paper (SNIP) 2018: 0.391

See all formats and pricing
More options …
Volume 220, Issue 10


A Comparative Study on the Electronic Structure of the 1-Ethyl-3-Methylimidazolium Bis(trifluoromethylsulfonyl)amide RT-Ionic Liquid by Electron Spectroscopy and First Principles Calculations

S. Krischok / R. Öttking / W. J. D. Beenken / M. Himmerlich / P. Lorenz / O. Höfft / S. Bahr / V. Kempter / J. A. Schaefer
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zpch.2006.220.10.1407

The near-surface electronic structure of the room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide has been investigated with ultraviolet and X-ray photoelectron spectroscopy as well as metastable induced electron spectroscopy. The results have been compared with density functional theory calculations. The good agreement between the experimental and theoretical data provides detailed insight into the origin of the observed spectral features. In particular, we found that a simple composition of the spectra of the isolated ions does not suffice to fit to the experimental results, but interionic interactions have to be considered.

: RT-Ionic Liquid; Electronic Structure; Density Functional Calculations; Photoelectron Spectroscopy (UPS, XPS); Metastable Induced Electron Spectroscopy (MIES)

About the article

Received: 2006-06-25

Accepted: 2006-08-10

Published Online: 2009-09-25

Published in Print: 2006-10-01

Citation Information: Zeitschrift für Physikalische Chemie, Volume 220, Issue 10, Pages 1407–1416, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.2006.220.10.1407.

Export Citation

© Oldenbourg Wissenschaftsverlag.Get Permission

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

Richard M. Fogarty, Robert G. Palgrave, Richard A. Bourne, Karsten Handrup, Ignacio J. Villar-Garcia, David J. Payne, Patricia A. Hunt, and Kevin R. J. Lovelock
Physical Chemistry Chemical Physics, 2019
Kaname KANAI
Journal of the Vacuum Society of Japan, 2013, Volume 56, Number 2, Page 61
Oliver HÖFFT, Stephan BAHR, and Volker KEMPTER
Analytical Sciences, 2008, Volume 24, Number 10, Page 1273
Yehia Khalifa, Alicia Broderick, and John T. Newberg
Journal of Electron Spectroscopy and Related Phenomena, 2017
F. Maier, I. Niedermaier, and H.-P. Steinrück
The Journal of Chemical Physics, 2017, Volume 146, Number 17, Page 170901
Ekaterina I. Izgorodina, Zoe L. Seeger, David L. A. Scarborough, and Samuel Y. S. Tan
Chemical Reviews, 2017, Volume 117, Number 10, Page 6696
I. Kuusik, M. Tarkanovskaja, J. Kruusma, V. Kisand, A. Tõnisoo, E. Lust, and E. Nõmmiste
Journal of Molecular Liquids, 2016, Volume 223, Page 939
Yuka Horikawa, Takashi Tokushima, Osamu Takahashi, Hiroshi Hoke, and Toshiyuki Takamuku
The Journal of Physical Chemistry B, 2016, Volume 120, Number 30, Page 7480
Inga Niedermaier, Claudia Kolbeck, Hans-Peter Steinrück, and Florian Maier
Review of Scientific Instruments, 2016, Volume 87, Number 4, Page 045105
H.-P. Steinrück, J. Libuda, P. Wasserscheid, T. Cremer, C. Kolbeck, M. Laurin, F. Maier, M. Sobota, P. S. Schulz, and M. Stark
Advanced Materials, 2011, Volume 23, Number 22-23, Page 2571
Lukáš Šištík, Milan Ončák, and Petr Slavíček
Physical Chemistry Chemical Physics, 2011, Volume 13, Number 25, Page 11998
Angela Keppler, Marcel Himmerlich, Tomonori Ikari, Marcel Marschewski, Evgenij Pachomow, Oliver Höfft, Wolfgang Maus-Friedrichs, Frank Endres, and Stefan Krischok
Phys. Chem. Chem. Phys., 2011, Volume 13, Number 3, Page 1174
Till Cremer, Claudia Kolbeck, Kevin R. J. Lovelock, Natalia Paape, René Wölfel, Peter S. Schulz, Peter Wasserscheid, Henry Weber, Jens Thar, Barbara Kirchner, Florian Maier, and Hans-Peter Steinrück
Chemistry - A European Journal, 2010, Volume 16, Number 30, Page 9018
F. Maier, T. Cremer, C. Kolbeck, K. R. J. Lovelock, N. Paape, P. S. Schulz, P. Wasserscheid, and H.-P. Steinrück
Physical Chemistry Chemical Physics, 2010, Volume 12, Number 8, Page 1905
Ignacio J. Villar-Garcia, Sarah Fearn, Gilbert F. De Gregorio, Nur L. Ismail, Florence J. V. Gschwend, Alastair J. S. McIntosh, and Kevin R. J. Lovelock
Chem. Sci., 2014, Volume 5, Number 11, Page 4404
Angela Ulbrich, Markus Reinmöller, Wichard J.D. Beenken, and Stefan Krischok
Journal of Molecular Liquids, 2014, Volume 192, Page 77
Angela Ulbrich, Markus Reinmöller, Wichard J. D. Beenken, and Stefan Krischok
ChemPhysChem, 2012, Volume 13, Number 7, Page 1718
Alasdair W. Taylor and Peter Licence
ChemPhysChem, 2012, Volume 13, Number 7, Page 1917
Hans-Peter Steinrück
Physical Chemistry Chemical Physics, 2012, Volume 14, Number 15, Page 5010
K. Kanai, T. Nishi, T. Iwahashi, Y. Ouchi, K. Seki, Y. Harada, and S. Shin
Journal of Electron Spectroscopy and Related Phenomena, 2009, Volume 174, Number 1-3, Page 110
Hans-Peter Steinrück
Surface Science, 2010, Volume 604, Number 5-6, Page 481
Markus Reinmöller, Angela Ulbrich, Tomonori Ikari, Julia Preiß, Oliver Höfft, Frank Endres, Stefan Krischok, and Wichard J. D. Beenken
Physical Chemistry Chemical Physics, 2011, Volume 13, Number 43, Page 19526
K. Kanai, T. Nishi, T. Iwahashi, Y. Ouchi, K. Seki, Y. Harada, and S. Shin
The Journal of Chemical Physics, 2008, Volume 129, Number 22, Page 224507

Comments (0)

Please log in or register to comment.
Log in