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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus

12 Issues per year


IMPACT FACTOR 2017: 1.144
5-year IMPACT FACTOR: 1.144

CiteScore 2017: 1.08

SCImago Journal Rank (SJR) 2017: 0.495
Source Normalized Impact per Paper (SNIP) 2017: 0.495

Online
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2196-7156
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Iron Cytochrome C Nanohybrids – Supramolecular Electron Transfer to an Electron Accepting Fullerene

Dirk M. Guldi / Israel Zilbermann / Maria Hatzimarinaki / Andreas Hirsch
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zpch.2006.220.4.487

Summary

For the first time, intracomplex electron transfer reactions were tested in cytochrome c based nanohybrids (i.e., Fe(II)CytC and Fe(III)CytC), to which polyanionic C60 derivatives were electrostatically associated. Successful radical ion pair formation, namely, oxidized FeCytC and reduced C60, was detected when divalent Fe(II)CytC is used. The so formed Fe(III)CytC · C60•− lives for 2.4 ± 0.5 μs.

Keywords: Cytochrome C; Fullerenes; Supramolecular Chemistry; Charge Separation; Photo-Induced Electron Transfer

About the article

Received: 2005-12-03

Accepted: 2005-12-20

Published Online: 2009-09-25

Published in Print: 2006-04-01


Citation Information: Zeitschrift für Physikalische Chemie, Volume 220, Issue 4/2006, Pages 487–495, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.2006.220.4.487.

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[1]
Ginka H. Sarova, Uwe Hartnagel, Domenico Balbinot, Sevda Sali, Norbert Jux, Andreas Hirsch, and Dirk M. Guldi
Chemistry - A European Journal, 2008, Volume 14, Number 10, Page 3137

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