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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus

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CiteScore 2018: 1.20

SCImago Journal Rank (SJR) 2018: 0.327
Source Normalized Impact per Paper (SNIP) 2018: 0.391

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Volume 222, Issue 1


Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 1: Frequency Modulation Spectroscopy

Gernot Friedrichs
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zpch.2008.222.1.1

Frequency modulation spectroscopy (FMS) and cavity ringdown spectroscopy (CRDS) are sensitive absorption based detection methods that have found widespread applications in gas phase reaction kinetics. In part 1 of this review, the theoretical foundations of FMS are addressed with a special emphasis on time-resolved quantitative measurements of concentration profiles. A complementary review of CRDS can be found in part 2 (Z. Phys. Chem. 222 (2008) 31–61). Practical aspects, possible pitfalls, attainable sensitivities, and modern trends are discussed. Kinetic studies based on FMS measurements as a time-resolved detection tool are briefly reviewed and a bibliography with more than a hundred entries is included to facilitate the access to the large body of original literature.

Keywords: Review; Frequency Modulation Spectroscopy; Time-Resolved; Reaction Kinetics

About the article

Received: 2007-09-05

Accepted: 2007-11-21

Published Online: 2009-09-25

Published in Print: 2008-01-01

Citation Information: Zeitschrift für Physikalische Chemie, Volume 222, Issue 1, Pages 1–30, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.2008.222.1.1.

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