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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Ed. by Rademann, Klaus

12 Issues per year

IMPACT FACTOR 2016: 1.012

CiteScore 2016: 0.99

SCImago Journal Rank (SJR) 2016: 0.463
Source Normalized Impact per Paper (SNIP) 2016: 0.470

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Volume 222, Issue 8-9 (Aug 2008)


Unusually Slow Intermolecular Proton-Deuteron Exchange in Porphycene

Piotr Fita / Natalia Urbanska / Czeslaw Radzewicz / Jacek Waluk
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zpch.2008.5380


The rates of the intermolecular exchange of two internal protons by deuterons have been determined for alcohol solutions of porphycene and its 2,7,12,17-tetra-t-butyl derivative using femtosecond pump-probe polarization spectroscopy. The process is very slow, requiring approximately twenty hours to substitute both protons by deuterons in more than 90% of the molecules dissolved in bulk EtOD or BuOD at 293 K. Equal rates were found for the exchange of the first and the second proton.

Keywords: Porphycene; Proton Transfer; Pump-Probe Polarized Spectroscopy

About the article

* Correspondence address: Polish Academy of Sciences , Institute of Physical Chemistry , Kasprzaka 44/52 , 01-224 Warsaw , Polen,

Published Online: 2009-09-25

Published in Print: 2008-08-01

Citation Information: Zeitschrift für Physikalische Chemie, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.2008.5380.

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