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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus


IMPACT FACTOR 2018: 0.975
5-year IMPACT FACTOR: 1.021

CiteScore 2018: 1.20

SCImago Journal Rank (SJR) 2018: 0.327
Source Normalized Impact per Paper (SNIP) 2018: 0.391

Online
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2196-7156
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Volume 224, Issue 7-8

Issues

Pressure Dependence of Iso-Propyl Nitrate Formation in the i-C3H7O2 + NO Reaction

N. I. Butkovskaya / A. Kukui
  • 1 Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS),, Verrières-le-Buisson, Frankreich
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/ G. Le Bras
  • 2 Institut de Combustion, Aérothermique, Réactivité et Environnement (ICARE), 45071 Orléans Cedex 2, Frankreich
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Published Online: 2010-08-03 | DOI: https://doi.org/10.1524/zpch.2010.6139

Abstract

The branching ratio β = k1b/k1a for the formation of iso-propyl nitrate, i-C3H7ONO2, in the gas-phase reaction of i-C3H7O2 with NO, i-C3H7O2 + NO → i-C3H7O + NO2 (1a), i-C3H7O2 + NO → i-C3H7ONO2 (1b), was determined over the pressure range 55–500 Torr at 298 K using a high-pressure turbulent flow reactor coupled with a chemical ionization quadrupole mass-spectrometer. The β coefficient was found to increase linearly with pressure from about 0.6% at 55 Torr to about 3% at 500 Torr. The atmospheric implication of the results obtained is briefly discussed.

Keywords: Iso-Propyl Nitrate; i-C3H7O2; NO; Reaction

About the article

* Correspondence address: Institute of Chemical Physics of, the Russian Academy of Sciences, Moscow, Russische Föderation,


Published Online: 2010-08-03

Published in Print: 2010-08-01


Citation Information: Zeitschrift für Physikalische Chemie, Volume 224, Issue 7-8, Pages 1025–1038, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.2010.6139.

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[1]
Sally E. Pusede, Allison L. Steiner, and Ronald C. Cohen
Chemical Reviews, 2015, Volume 115, Number 10, Page 3898
[2]
N. I. Butkovskaya, A. Kukui, G. Le Bras, M.-T. Rayez, and J.-C. Rayez
The Journal of Physical Chemistry A, 2015, Volume 119, Number 19, Page 4408
[3]
A. E. Perring, S. E. Pusede, and R. C. Cohen
Chemical Reviews, 2013, Volume 113, Number 8, Page 5848
[4]
John J. Orlando and Geoffrey S. Tyndall
Chemical Society Reviews, 2012, Volume 41, Number 19, Page 6294
[5]
Nadezhda Butkovskaya, Alexandre Kukui, and Georges Le Bras
The Journal of Physical Chemistry A, 2012, Volume 116, Number 24, Page 5972

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