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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Ed. by Rademann, Klaus

12 Issues per year


IMPACT FACTOR 2016: 1.012

CiteScore 2016: 0.99

SCImago Journal Rank (SJR) 2015: 0.491
Source Normalized Impact per Paper (SNIP) 2015: 0.520

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ISSN
2196-7156
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In This Section
Volume 225, Issue 9-10 (Oct 2011)

Issues

Combustion Chemistry of the Butane Isomers in Premixed Low-Pressure Flames

Patrick Oßwald / Katharina Kohse-Höinghaus
  • 1 Bielefeld University, Department of Chemistry, Bielefeld, Deutschland
/ Ulf Struckmeier
  • 2 Thermo Fisher Scientific, Solaar House, Cambridge, CB5 8BZ, Großbritannien
/ Thomas Zeuch
  • 3 Universität Göttingen, Institut für Physikalische Chemie, Göttingen, Deutschland
/ Lars Seidel
  • 4 Brandenburg University of Technology, Thermodynamics and Thermal Process Engineering, Cottbus, Deutschland
/ Larisa Leon
  • 5 Brandenburg University of Technology, Thermodynamics and Thermal Process Engineering, Cottbus, Deutschland
/ Fabian Mauss
  • 6 Brandenburg University of Technology, Thermodynamics and Thermal Process Engineering, Cottbus, Deutschland
Published Online: 2011-10-06 | DOI: https://doi.org/10.1524/zpch.2011.0148

Abstract

The combustion chemistry of the two butane isomers represents a subset in a comprehensive description of C1–C4 hydrocarbon and oxygenated fuels. A critical examination of combustion models and their capability to predict emissions from this class of fuels must rely on high-quality experimental data that address the respective chemical decomposition and oxidation pathways, including quantitative intermediate species mole fractions. Premixed flat low-pressure (40 mbar) flames of the two butane isomers were thus studied under identical, fuel-rich (φ=1.71) conditions. Two independent molecular-beam mass spectrometer (MBMS) set-ups were used to provide quantitative species profiles. Both data sets, one from electron ionization (EI)-MBMS with high mass resolution and one from photoionization (PI)-MBMS with high energy resolution, are in overall good agreement. Simulations with a flame model were used to analyze the respective reaction pathways, and differences in the combustion behavior of the two isomers are discussed.

Keywords: Butane Combustion Chemistry; Premixed Laminar Low-Pressure Flames; Molecular-Beam Mass Spectrometry; Kinetic Modeling

About the article

* Correspondence address: Bielefeld University, Department of Chemistry, Universitätsstr. 25, 33615 Bielefeld, Deutschland,


Published Online: 2011-10-06

Published in Print: 2011-10-01



Citation Information: Zeitschrift für Physikalische Chemie, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1524/zpch.2011.0148. Export Citation

Citing Articles

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[1]
Markus Köhler, Patrick Oßwald, Hongbin Xu, Trupti Kathrotia, Christian Hasse, and Uwe Riedel
Chemical Engineering Science, 2015
[2]
Patrick Oßwald and Markus Köhler
Review of Scientific Instruments, 2015, Volume 86, Number 10, Page 105109
[3]
Markus Köhler, Trupti Kathrotia, Patrick Oßwald, Marileen L. Fischer-Tammer, Kai Moshammer, and Uwe Riedel
Combustion and Flame, 2015
[4]
Lars Seidel, Kai Moshammer, Xiaoxiao Wang, Thomas Zeuch, Katharina Kohse-Höinghaus, and Fabian Mauss
Combustion and Flame, 2015, Volume 162, Number 5, Page 2045
[5]
Zhandong Wang, Xiaoyuan Zhang, Lili Xing, Lidong Zhang, Friederike Herrmann, Kai Moshammer, Fei Qi, and Katharina Kohse-Höinghaus
Combustion and Flame, 2015, Volume 162, Number 4, Page 1113
[6]
Julia Krüger, Gustavo A. Garcia, Daniel Felsmann, Kai Moshammer, Alexander Lackner, Andreas Brockhinke, Laurent Nahon, and Katharina Kohse-Höinghaus
Phys. Chem. Chem. Phys., 2014, Volume 16, Number 41, Page 22791
[7]
M. Schenk, N. Hansen, H. Vieker, A. Beyer, A. Gölzhäuser, and K. Kohse-Höinghaus
Proceedings of the Combustion Institute, 2015, Volume 35, Number 2, Page 1761
[8]
A. Nawdiyal, N. Hansen, T. Zeuch, L. Seidel, and F. Mauß
Proceedings of the Combustion Institute, 2015, Volume 35, Number 1, Page 325
[9]
P. Oßwald, P. Hemberger, T. Bierkandt, E. Akyildiz, M. Köhler, A. Bodi, T. Gerber, and T. Kasper
Review of Scientific Instruments, 2014, Volume 85, Number 2, Page 025101
[10]
Sijie Li, Ashley Campos, David F. Davidson, and Ronald K. Hanson
Fuel, 2014, Volume 118, Page 398
[11]
Friederike Herrmann, Bernhard Jochim, Patrick Oßwald, Liming Cai, Heinz Pitsch, and Katharina Kohse-Höinghaus
Combustion and Flame, 2014, Volume 161, Number 2, Page 384
[12]
Kai Moshammer, Stijn Vranckx, Harish K. Chakravarty, Prajakta Parab, Ravi X. Fernandes, and Katharina Kohse-Höinghaus
Combustion and Flame, 2013, Volume 160, Number 12, Page 2729
[13]
Casimir Togbé, Luc-Sy Tran, Dong Liu, Daniel Felsmann, Patrick Oßwald, Pierre-Alexandre Glaude, Baptiste Sirjean, René Fournet, Frédérique Battin-Leclerc, and Katharina Kohse-Höinghaus
Combustion and Flame, 2014, Volume 161, Number 3, Page 780
[14]
Luc-Sy Tran, Casimir Togbé, Dong Liu, Daniel Felsmann, Patrick Oßwald, Pierre-Alexandre Glaude, René Fournet, Baptiste Sirjean, Frédérique Battin-Leclerc, and Katharina Kohse-Höinghaus
Combustion and Flame, 2014, Volume 161, Number 3, Page 766
[15]
Marina Schenk, Larisa Leon, Kai Moshammer, Patrick Oßwald, Thomas Zeuch, Lars Seidel, Fabian Mauss, and Katharina Kohse-Höinghaus
Combustion and Flame, 2013, Volume 160, Number 3, Page 487
[16]
P.A. Skovorodko, A.G. Tereshchenko, O.P. Korobeinichev, D.A. Knyazkov, and A.G. Shmakov
Combustion Theory and Modelling, 2013, Volume 17, Number 1, Page 1
[17]
Elke Goos, Christina Sickfeld, Fabian Mauß, Lars Seidel, Branko Ruscic, Alexander Burcat, and Thomas Zeuch
Proceedings of the Combustion Institute, 2013, Volume 34, Number 1, Page 657
[18]
Kuiwen Zhang, Kai Moshammer, Patrick Oβwald, and Katharina Kohse-Höinghaus
Proceedings of the Combustion Institute, 2013, Volume 34, Number 1, Page 763
[19]
F. Herrmann, P. Oßwald, and K. Kohse-Höinghaus
Proceedings of the Combustion Institute, 2013, Volume 34, Number 1, Page 771
[20]
Alessio Frassoldati, Roberto Grana, Tiziano Faravelli, Eliseo Ranzi, Patrick Oßwald, and Katharina Kohse-Höinghaus
Combustion and Flame, 2012, Volume 159, Number 7, Page 2295

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