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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus

12 Issues per year


IMPACT FACTOR 2017: 1.144
5-year IMPACT FACTOR: 1.144

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Online
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2196-7156
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Volume 228, Issue 4-5

Issues

Far-IR Spectra of Small Neutral Gold Clusters in the Gas Phase

Philipp Gruene / Burkhard Butschke
  • Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany
  • present address: Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot, Israel
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jonathan T. Lyon
  • Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany
  • Department of Natural Sciences, Clayton State University, 2000 Clayton State Blvd., Morrow, Georgia 30260, USA
  • Other articles by this author:
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/ David M. Rayner / André Fielicke
  • Corresponding author
  • Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin, Germany
  • Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany
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  • Other articles by this author:
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Published Online: 2014-02-07 | DOI: https://doi.org/10.1515/zpch-2014-0480

Abstract

Vibrational spectra of small neutral gold clusters containing up to 8 Au atoms are measured in the far-infrared (46–222 cm1) via photodissociation of their complexes with krypton atoms. Comparisons with calculated IR spectra for bare Aun clusters using density functional theory allow for structural assignment. For these small sizes, all clusters are found to be planar and of comparably high symmetry. For Au6 no data is available, as this cluster size is not detected in the photoionization mass spectra due to its high ionization energy. The structures assigned are for n = 4: rhombus (D2h); 5: trapezoid (C2v); 7: edge-capped triangle (Cs), 8: 4-fold edge-capped square (D4h).

Keywords: Vibrational Spectroscopy; Metal Clusters; Structure Determination; Multiple Photon Dissociation; Far-Infrared

About the article

Accepted: 2013-12-17

Received: 2013-11-01

Published Online: 2014-02-07

Published in Print: 2014-05-28


Citation Information: Zeitschrift für Physikalische Chemie, Volume 228, Issue 4-5, Pages 337–350, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2014-0480.

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