Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus

12 Issues per year


IMPACT FACTOR 2017: 1.144
5-year IMPACT FACTOR: 1.144

CiteScore 2017: 1.08

SCImago Journal Rank (SJR) 2017: 0.495
Source Normalized Impact per Paper (SNIP) 2017: 0.495

Online
ISSN
2196-7156
See all formats and pricing
More options …
Volume 231, Issue 3

Issues

SABRE Hyperpolarization of Bipyridine Stabilized Ir-Complex at High, Low and Ultralow Magnetic Fields

Andrey N. Pravdivtsev
  • Corresponding author
  • International Tomography Center, Institutskaya 3A, Novosibirsk, 630090, Russia
  • Novosibirsk State University, Pirogova 2, Novosibirsk, 630090, Russia, Tel.: +7(383)330-8868, Fax: +7(383)333-1399
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2016-08-26 | DOI: https://doi.org/10.1515/zpch-2016-0810

Abstract

A strong limitation of nuclear magnetic resonance is its low inherent sensitivity that can be overcome by using an appropriate hyperpolarization technique. Presently, dynamic nuclear polarization and spin-exchange optical pumping are the only hyperpolarization techniques that are used in applied medicine. However, both are relatively complex in use and expensive. Here we present a modification of the signal amplification by reversible exchange (SABRE) hyperpolarization method – SABRE on stabilized Ir-complexes. A stabilized Ir-complex (here we used bipyridine for stabilization) can be hyperpolarized in a wide range of magnetic fields from a few μT upto 10 T with 15N polarization of about 1–3%. Moreover, the investigated complex can be incorporated into biomolecules or other bulky molecules; in this situation exchange with para-hydrogen will allow one to continuously generate hyperpolarization.

This article offers supplementary material which is provided at the end of the article.

Keywords: bipyridine; NMR; para-hydrogen; SABRE

Dedicated to: Kev Salikhov on the occasion of his 80th birthday.

References

  • 1.

    K. H. Hausser, D. Stehlik, Advances in Magnetic Resonance, (J. S. Waugh Ed.) Academic, New York (1968), P. 79.Google Scholar

  • 2.

    C. Griesinger, M. Bennati, H.-M. Vieth, C. Luchinat, G. Parigi, P. Höfer, F. Engelke, S. J. Glaser, V. Denysenkov, T. F. Prisner, Prog. Nucl. Magn. Reson. Spectrosc. 64 (2012) 4.Google Scholar

  • 3.

    T. Maly, G. T. Debelouchina, V. S. Bajaj, K.-N. Hu, C.-G. Joo, M. L. Mak-Jurkauskas, J. R. Sirigiri, P. C. A. van der Wel, J. Herzfeld, R. J. Temkin, R. G. Griffin, J. Chem. Phys. 128 (2008) 052211.Google Scholar

  • 4.

    W. Happer, Rev. Mod. Phys. 44 (1972) 169.Google Scholar

  • 5.

    D. Stehlik, H.-M. Vieth, Mol. Cryst. Liq. Cryst. 93 (1983) 83.Google Scholar

  • 6.

    J. Natterer, J. Bargon, Prog. Nucl. Magn. Reson. Spectrosc. 31 (1997) 293.Google Scholar

  • 7.

    R. A. Green, R. W. Adams, S. B. Duckett, R. E. Mewis, D. C. Williamson, G. G. R. Green, Prog. Nucl. Magn. Reson. Spectrosc. 67 (2012) 1.Google Scholar

  • 8.

    R. W. Adams, J. A. Aguilar, K. D. Atkinson, M. J. Cowley, P. I. P. Elliott, S. B. Duckett, G. G. R. Green, I. G. Khazal, J. López-Serrano, D. C. Williamson, Science 323 (2009) 1708.Google Scholar

  • 9.

    M. J. Cowley, R. W. Adams, K. D. Atkinson, M. C. R. Cockett, S. B. Duckett, G. G. R. Green, J. A. B. Lohman, R. Kerssebaum, D. Kilgour, R. E. Mewis, J. Am. Chem. Soc. 133 (2011) 6134.Google Scholar

  • 10.

    A. N. Pravdivtsev, A. V. Yurkovskaya, H.-M. Vieth, K. L. Ivanov, R. Kaptein, ChemPhysChem 14 (2013) 3327.Google Scholar

  • 11.

    E. B. Dücker, L. T. Kuhn, K. Münnemann, C. Griesinger, J. Magn. Reson. 214 (2012) 159.Google Scholar

  • 12.

    A. N. Pravdivtsev, A. V. Yurkovskaya, H. Zimmermann, H. M. Vieth, K. L. Ivanov, Rsc Advances 5 (2015) 63615.Google Scholar

  • 13.

    T. Theis, M. L. Truong, A. M. Coffey, R. V. Shchepin, K. W. Waddell, F. Shi, B. M. Goodson, W. S. Warren, E. Y. Chekmenev, J. Am. Chem. Soc. 137 (2015) 1404.Google Scholar

  • 14.

    T. Theis, M. Truong, A. M. Coffey, E. Y. Chekmenev, W. S. Warren, J. Magn. Reson. 248 (2014) 23.Google Scholar

  • 15.

    N. Eshuis, R. L. E. G. Aspers, B. J. A. van Weerdenburg, M. C. Feiters, F. P. J. T. Rutjes, S. S. Wijmenga, M. Tessari, Angew. Chem. Int. Ed. 54 (2015) 14527.Google Scholar

  • 16.

    A. N. Pravdivtsev, A. V. Yurkovskaya, H. M. Vieth, K. L. Ivanov, Phys. Chem. Chem. Phys. 16 (2014) 24672.Google Scholar

  • 17.

    A. N. Pravdivtsev, A. V. Yurkovskaya, H.-M. Vieth, K. L. Ivanov, J. Phys. Chem. B 119 (2015) 13619.Google Scholar

  • 18.

    J. B. Hövener, S. Bär, J. Leupold, K. Jenne, D. Leibfritz, J. Hennig, S. B. Duckett, D. von Elverfeldt, NMR Biomed. 26 (2013) 124.Google Scholar

  • 19.

    J. B. Hövener, N. Schwaderlapp, T. Lickert, S. B. Duckett, R. E. Mewis, L. A. R. Highton, S. M. Kenny, G. G. R. Green, D. Leibfritz, J. G. Korvink, J. Hennig, D. von Elverfeldt, Nat. Commun. 4 (2013) 2946.Google Scholar

  • 20.

    J. B. Hövener, N. Schwaderlapp, R. Borowiak, T. Lickert, S. B. Duckett, R. E. Mewis, R. W. Adams, M. J. Burns, L. A. R. Highton, G. G. R. Green, A. Olaru, J. Hennig, D. von Elverfeldtt, Anal. Chem. 86 (2014) 1767.Google Scholar

  • 21.

    R. E. Mewis, M. Fekete, G. G. R. Green, A. C. Whitwood, S. B. Duckett, Chem. Commun. 51 (2015) 9857.Google Scholar

  • 22.

    T. Theis, G. X. Ortiz, A. W. J. Logan, K. E. Claytor, Y. Feng, W. P. Huhn, V. Blum, S. J. Malcolmson, E. Y. Chekmenev, Q. Wang, W. S. Warren, Sci. Adv. 2 (2016).Google Scholar

  • 23.

    I. Kownacki, M. Kubicki, K. Szubert, B. Marciniec, J. Organomet. Chem. 693 (2008) 321.Google Scholar

  • 24.

    A. S. Kiryutin, A. N. Pravdivtsev, K. L. Ivanov, Y. A. Grishin, H.-M. Vieth, A. V. Yurkovskaya, J. Magn. Reson. 263 (2016) 79.Google Scholar

  • 25.

    M. L. Truong, T. Theis, A. M. Coffey, R. V. Shchepin, K. W. Waddell, F. Shi, B. M. Goodson, W. S. Warren, E. Y. Chekmenev, J. Phys. Chem. C 119 (2015) 8786.Google Scholar

  • 26.

    K. L. Ivanov, A. N. Pravdivtsev, A. V. Yurkovskaya, H.-M. Vieth, R. Kaptein, Prog. Nucl. Magn. Reson. Spectros. 81 (2014) 1.Google Scholar

  • 27.

    A. N. Pravdivtsev, K. L. Ivanov, A. V. Yurkovskaya, P. A. Petrov, H.-H. Limbach, R. Kaptein, and H.-M. Vieth, J. Magn. Reson. 261 (2015) 73.Google Scholar

  • 28.

    M. Fekete, O. Bayfield, S. B. Duckett, S. Hart, R. E. Mewis, N. Pridmore, P. J. Rayner, A. Whitwood, Inorg. Chem. 52 (2013) 13453.Google Scholar

  • 29.

    S. Gloggler, R. Muller, J. Colell, M. Emondts, M. Dabrowski, B. Blumich, S. Appelt, Phys. Chem. Chem. Phys. 13 (2011) 13759.Google Scholar

  • 30.

    H. Zeng, J. Xu, J. Gillen, M. T. McMahon, D. Artemov, J.-M. Tyburn, J. A. B. Lohman, R. E. Mewis, K. D. Atkinson, G. G. R. Green, S. B. Duckett, P. C. M. van Zijl, J. Magn. Reson. 237 (2013) 73.Google Scholar

  • 31.

    V. Daniele, F.-X. Legrand, P. Berthault, J.-N. Dumez, G. Huber, ChemPhysChem 16 (2015) 3413.Google Scholar

  • 32.

    H. F. Zeng, J. D. Xu, M. T. McMahon, J. A. B. Lohman, P. C. M. van Zijl, J. Magn. Reson. 246 (2014) 119.Google Scholar

  • 33.

    D. A. Barskiy, K. V. Kovtunov, I. V. Koptyug, P. He, K. A. Groome, Q. A. Best, F. Shi, B. M. Goodson, R. V. Shchepin, A. M. Coffey, K. W. Waddell, E. Y. Chekmenev, J. Am. Chem. Soc. 136 (2014) 3322.Google Scholar

  • 34.

    A. S. Kiryutin, A. V. Yurkovskaya, N. N. Lukzen, H.-M. Vieth, K. L. Ivanov, J. Chem. Phys. 143 (2015) 234203.Google Scholar

  • 35.

    S. J. DeVience, R. L. Walsworth, M. S. Rosen, Phys. Rev. Lett. 111 (2013) 173002.Google Scholar

  • 36.

    A. N. Pravdivtsev, A. V. Yurkovskaya, N. N. Lukzen, H. M. Vieth, K. L. Ivanov, Phys. Chem. Chem. Phys. 16 (2014) 18707.Google Scholar

  • 37.

    T. Theis, Y. Feng, T. Wu, W. S. Warren, J. Chem. Phys. 140 (2014) 014201.Google Scholar

  • 38.

    D. A. Barskiy, A. N. Pravdivtsev, K. L. Ivanov, K. V. Kovtunov, I. V. Koptyug, Phys. Chem. Chem. Phys. 18 (2016) 89.Google Scholar

About the article

Received: 2016-06-06

Accepted: 2016-07-15

Published Online: 2016-08-26

Published in Print: 2017-03-01


Citation Information: Zeitschrift für Physikalische Chemie, Volume 231, Issue 3, Pages 497–511, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2016-0810.

Export Citation

©2017 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Supplementary Article Materials

Comments (0)

Please log in or register to comment.
Log in