Abstract
The synthesis of novel robust and stable iridium-based immobilized catalysts on silica-polymer hybrid materials (Si-PB-Ir) is described. These catalysts are characterized by a combination of 1D 31P CP-MAS and 2D 31P-1H HETCOR and J-resolved multinuclear solid state NMR experiments. Different binding situations such as singly and multiply coordinated phosphines are identified. Density functional theory (DFT) calculations are performed to corroborate the interpretation of the experimental NMR data, in order to propose a structural model of the heterogenized catalysts. Finally, the catalytic activity of the Si-PB-Ir catalysts is investigated for the hydrogenation of styrene employing para-enriched hydrogen gas.
Dedicated to: Prof. Kev Salikhov on the occasion of his 80th birthday.
Acknowledgments
Financial support by the Deutsche Forschungsgemeinschaft under contract BU-911-22-1 is gratefully acknowledged. We thank Ömer Faruk Delibalta for the help in the synthesis of the materials.
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