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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus


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Volume 231, Issue 3

Issues

31P-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts

Torsten Gutmann
  • Technische Universität Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
  • Other articles by this author:
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/ Safaa Alkhagani
  • Technische Universität Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Niels Rothermel
  • Technische Universität Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Hans-Heinrich Limbach
  • Freie Universität Berlin, FB Biologie, Chemie, Pharmazie, Takustr. 3, D-14195 Berlin, Germany
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/ Hergen Breitzke
  • Technische Universität Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Gerd Buntkowsky
  • Corresponding author
  • Technische Universität Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
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Published Online: 2016-10-27 | DOI: https://doi.org/10.1515/zpch-2016-0837

Abstract

The synthesis of novel robust and stable iridium-based immobilized catalysts on silica-polymer hybrid materials (Si-PB-Ir) is described. These catalysts are characterized by a combination of 1D 31P CP-MAS and 2D 31P-1H HETCOR and J-resolved multinuclear solid state NMR experiments. Different binding situations such as singly and multiply coordinated phosphines are identified. Density functional theory (DFT) calculations are performed to corroborate the interpretation of the experimental NMR data, in order to propose a structural model of the heterogenized catalysts. Finally, the catalytic activity of the Si-PB-Ir catalysts is investigated for the hydrogenation of styrene employing para-enriched hydrogen gas.

This article offers supplementary material which is provided at the end of the article.

Keywords: DFT; heterogeneous catalysis; hydrogenation; iridium; PHIP; solid-state-NMR

Dedicated to: Prof. Kev Salikhov on the occasion of his 80th birthday.

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About the article

Received: 2016-06-28

Accepted: 2016-10-05

Published Online: 2016-10-27

Published in Print: 2017-03-01


Citation Information: Zeitschrift für Physikalische Chemie, Volume 231, Issue 3, Pages 653–669, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2016-0837.

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