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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus


IMPACT FACTOR 2018: 0.975
5-year IMPACT FACTOR: 1.021

CiteScore 2018: 1.20

SCImago Journal Rank (SJR) 2018: 0.327
Source Normalized Impact per Paper (SNIP) 2018: 0.391

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2196-7156
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Volume 231, Issue 3

Issues

Toward Matching Optically and NMR Active Volumes for Optimizing the Observation of Photo-Induced Reactions by NMR

Eduard Stadler
  • Institute of Physical and Theoretical Chemistry, TU Graz, NAWI Graz, Stremayrgasse 9, A-8010 Graz, Austria
  • Other articles by this author:
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/ Anna Eibel
  • Institute of Physical and Theoretical Chemistry, TU Graz, NAWI Graz, Stremayrgasse 9, A-8010 Graz, Austria
  • Other articles by this author:
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/ Dmytro Neshchadin
  • Institute of Physical and Theoretical Chemistry, TU Graz, NAWI Graz, Stremayrgasse 9, A-8010 Graz, Austria
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/ Georg Gescheidt
  • Corresponding author
  • Institute of Physical and Theoretical Chemistry, TU Graz, NAWI Graz, Stremayrgasse 9, A-8010 Graz, Austria
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Published Online: 2016-10-15 | DOI: https://doi.org/10.1515/zpch-2016-0854

Abstract

In the recent years photo-induced reactions are becoming increasingly popular in many fields of chemistry comprising biological conversions, material/environmental science and synthesis. NMR monitoring of such reactions has been shown being advantageous and several strategies of providing an efficient irradiation of the NMR sample have been developed and reported. Here we show that adjusting the optical properties of the investigated solution to the active volume detected by the NMR experiment is valuable. This is shown with the help of three examples comprising photo-isomerization, photo-induced polymerization and CIDNP-detected bond cleavage. Adjusting the photo-active volume to the NMR-detectable portion of the sample provides a substantially more realistic kinetic information, background suppression and reduction of thermal and diffusional effects.

Keywords: CIDNP; NMR; photochemistry; photo-induced reactions

Dedicated to: Kev Salikhov on the occasion of his 80th birthday.

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About the article

Received: 2016-07-13

Accepted: 2016-09-21

Published Online: 2016-10-15

Published in Print: 2017-03-01


Citation Information: Zeitschrift für Physikalische Chemie, Volume 231, Issue 3, Pages 625–636, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2016-0854.

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