Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus


IMPACT FACTOR 2017: 1.144
5-year IMPACT FACTOR: 1.144

CiteScore 2017: 1.08

SCImago Journal Rank (SJR) 2017: 0.495
Source Normalized Impact per Paper (SNIP) 2017: 0.495

Online
ISSN
2196-7156
See all formats and pricing
More options …
Volume 232, Issue 5-6

Issues

Influence of Local Environment on Inner Shell Excitation Spectra, Studied by Electron and X-ray Spectroscopy and Spectromicroscopy

Adam P. Hitchcock
  • Corresponding author
  • Department of Chemistry and Chemical Biology, McMaster University, Hamilton, ON L8S 4M1, Canada, Phone: +1 905 525-9140
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2017-12-09 | DOI: https://doi.org/10.1515/zpch-2017-1061

Abstract

Inner shell excitation spectroscopy is a local probe of the unoccupied electronic structure in the immediate vicinity of the core excited atom. As such, one might expect the inner shell spectrum of a given unit (a molecular fragment or a repeat unit of a solid) to be largely independent of where that unit is located. This is often an implicit assumption in spectral analysis and analytical applications. However, there are situations where inner shell excitation spectra exhibit significant sensitivity to their local environment. Here I categorize the ways in which inner shell spectra are affected by their local environment, and give examples from a career dedicated to developing a better understanding of inner shell excitation spectroscopy, its experimental techniques, and applications.

Keywords: electron energy loss; inner shell excitation spectroscopy; STXM; X-ray absorption

Dedicated to: Eckart Rühl on the occasion of his 60th birthday.

References

  • 1.

    A. P. Hitchcock, Phys. Scripta T31 (1990) 159.CrossrefGoogle Scholar

  • 2.

    A. P. Hitchcock, J. Electron Spectroscopy Rel. Phenom. 112 (2000) 9.CrossrefGoogle Scholar

  • 3.

    J. Stöhr, NEXAFS spectroscopy, Springer, Berlin (1992).Google Scholar

  • 4.

    A. R. Milosavljević, A. Giuliani, C. Nicolas, Chapter 8, in: X-ray and Neutron Techniques for Nanomaterials Characterization, C. S. S. R. Kumar (Ed.), Springer-Verlag, Berlin (2016).Google Scholar

  • 5.

    M. B. Casu, T. Chassé, NEXAFS studies at surfaces, in: Handbook of Spectroscopy, 2nd ed. G. Gauglitz, D. S. Moore (Eds.), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany (2014).Google Scholar

  • 6.

    X. Liu, W. Yang, Z. Liu, Adv. Mater 2 (2014) 7710.Google Scholar

  • 7.

    T. Plashkevych, H. Privalov, H. Agren, V. Carravetta, K. Ruud, Chem. Phys 260 (2000) 11.CrossrefGoogle Scholar

  • 8.

    Ph. Wernet, D. Nordlund, U. Bergmann, M. Cavalleri, M. Odelius, H. Ogasawara, L. Å. Naslund, T. K. Hirsch, L. Ojamae, P. Glatzel, L. G. M. Pettersson, A. Nilsson, Science 304 (2004) 995.PubMedCrossrefGoogle Scholar

  • 9.

    M. Iannuzzi, J. Hutter, Phys. Chem. Chem. Phys. 9 (2007) 1599.PubMedCrossrefGoogle Scholar

  • 10.

    M. S. Schöffler, J. Titze, N. Petridis, T. Jahnke, K. Cole, L. P. Schmidt, A. Czasch, D. Akoury, O. Jagutzki, J. B. Williams, N. A. Cherepkov, S. K. Semenov, C. W. McCurdy, T. N. Rescigno, C. L. Cocke, T. Osipo, S. Lee, M. H. Prior, A. Belkacem, A. L. Landers, H. Schmidt-Böcking, T. Weber, R. Dörner, Science 320 (2008) 920.CrossrefPubMedGoogle Scholar

  • 11.

    L. Triguero, L. G. M. Pettersson, H. Agren, Phys. Rev. B 58 (1998) 8097.CrossrefGoogle Scholar

  • 12.

    M. Newville, Rev. Mineral. Geochem. 78 (2014) 33.CrossrefGoogle Scholar

  • 13.

    I. N. Levine, Quantum Mechanics, 7th ed. Pearson, NY (2013).Google Scholar

  • 14.

    F. Sette, J. Stöhr, A. P. Hitchcock, J. Chem. Phys. 81 (1984) 4906.CrossrefGoogle Scholar

  • 15.

    G. Cooper, M. Gordon, D. Tulumello, C. C. Turci, K. Kaznatcheev, A. P. Hitchcock, J. Electron Spectroscopy Rel. Phenom. 137–140 (2004) 795.Google Scholar

  • 16.

    J. R. Lawrence, G. D. W. Swerhone, G. G. Leppard, T. Araki, X. Zhang, M. M. West, A. P. Hitchcock, Appl. Environ. Microbiol. 69 (2003) 5543.PubMedCrossrefGoogle Scholar

  • 17.

    R. F. Egerton, Rep. Prog. Phys. 72 (2009) 016502.CrossrefGoogle Scholar

  • 18.

    R. McLaren, S. A. C. Clark, I. Ishii, A. P. Hitchcock, Phys. Rev. A 36 (1987) 1683.CrossrefGoogle Scholar

  • 19.

    Hitchcock. 2017. database: http://unicorn.mcmaster.ca/corex/cedb-title.html; bibliography: http://unicorn.mcmaster.ca/xrm-biblio/xrm_bib.html. Accessed 20 October 2017.

  • 20.

    H. Ade, A. P. Hitchcock, Polymer 49 (2008) 643.CrossrefGoogle Scholar

  • 21.

    A. P. Hitchcock, Chapter 22, in: Volume II of the Handbook on Nanoscopy, G. Van Tendeloo, D. Van Dyck, S. J. Pennycook (Eds.), Wiley, New York (2012), p. 745.Google Scholar

  • 22.

    W. Chao, P. Fischer, T. Tyliszczak, S. Rekawa, E. Anderson, P. Naulleau, Opt Express 20 (2012) 9777.CrossrefPubMedGoogle Scholar

  • 23.

    A. L. D. Kilcoyne, T. Tylisczak, W. F. Steele, S. Fakra, P. Hitchcock, K. Franck, E. Anderson, B. Harteneck, E. G. Rightor, G. E. Mitchell, A. P. Hitchcock, L. Yang, T. Warwick, H. Ade, J. Synchrotron Radiat. 10 (2003) 125.CrossrefPubMedGoogle Scholar

  • 24.

    T. Warwick, H. Ade, A. L. D. Kilcoyne, M. Kritscher, T. Tylisczcak, S. Fakra, A. P. Hitchcock, P. Hitchcock, H. A. Padmore, J. Synchrotron Radiat. 9 (2002) 254.CrossrefPubMedGoogle Scholar

  • 25.

    K. V. Kaznatcheev, Ch. Karunakaran, U. D. Lanke, S. G. Urquhart, M. Obst, A.P. Hitchcock, Nucl. Inst. Meth. A 582 (2007) 96.CrossrefGoogle Scholar

  • 26.

    C. Jacobsen, S. Wirick, G. Flynn, C. Zimba, J. Microscopy 197 (2000)173.CrossrefGoogle Scholar

  • 27.

    A. P. Hitchcock, aXis2000 is written in Interactive Data Language (IDL). It is available free for non-commercial use from http://unicorn.mcmaster.ca/aXis2000.html. Accessed 20 October 2017.

  • 28.

    J. Liu, Y. Zhang, M. I. Ionescu, R. Li, X. Sun, Appl. Surf. Sci. 257 (2011) 7837.CrossrefGoogle Scholar

  • 29.

    E. Rühl, C. Heinzel, A. P. Hitchcock, H. Baumgärtel, J. Chem. Phys. 98 (1993) 2653.CrossrefGoogle Scholar

  • 30.

    E. Rühl, C. Heinzel, A. P. Hitchcock, H. Schmeltz, C. Reynaud, H. Baumgärtel, W. Drube, R. Frahm, J. Chem. Phys. 98 (1993) 6820.CrossrefGoogle Scholar

  • 31.

    M. O. Krause, C. D. Caldwell, A. Menzel, S. Benzaud, J. Jiminez-Mier, J. Electron Spectroscopy Rel. Phenom. 79 (1996) 241.CrossrefGoogle Scholar

  • 32.

    A. P. Hitchcock, C. E. Brion, J. Electron Spectroscopy Rel. Phenom. 18 (1980) 1.CrossrefGoogle Scholar

  • 33.

    E. Rühl, A. P. Hitchcock, Chem. Phys. 154 (1991) 323.CrossrefGoogle Scholar

  • 34.

    K. L. Harding, S. Kalirai, R. Hayes, V. Ju, G. Cooper, A. P. Hitchcock, M. R. Thompson, Chem. Phys. 461 (2015) 117.CrossrefGoogle Scholar

  • 35.

    K. J. Randall, W. Eberhardt, J. Feldhaus, W. Erlebach, A. M. Bradshaw, Z. Xu, P. D. Johnson, Y. Ma, Nucl. Inst. Meth. A 319 (1992) 101.CrossrefGoogle Scholar

  • 36.

    A. Kivimaki, B. Kempgens, M. N. Piancastelli, M. Neeb, K. Maier, A, Rudel, U. Hergerhahn, A. M. Bradshaw, J. Electron Spectroscopy Rel. Phenom. 93 (1998) 81.CrossrefGoogle Scholar

  • 37.

    E. Rühl, Int. J. Mass Spectrom. 229 (2003) 117.CrossrefGoogle Scholar

  • 38.

    R. Flesch, A. A. Pavlychev, J. J. Neville, J. Blumberg, M. Kuhlmann, W. Tappe, F. Senf, O. Schwarzkopf, A. P. Hitchcock, E. Rühl, Phys. Rev. Lett. 86 (2001) 3767.CrossrefPubMedGoogle Scholar

  • 39.

    R. Flesch, N. Kosugi, I. Bradeanu, J. J. Neville, E. Rühl, J. Chem. Phys. 121 (2004) 8343.CrossrefPubMedGoogle Scholar

  • 40.

    J. Zhou, J. Wang, H. Liu, M. N. Banis, X. Sun, T. K. Sham, J. Phys. Chem. Lett. 1 (2010) 1709.CrossrefGoogle Scholar

  • 41.

    S. Stamboula, PhD thesis, McMaster University, Hamilton, Canada, 2018.Google Scholar

  • 42.

    R. Flesch, E. Serdaroglu, F. Blobner, P. Feulner, X. O. Brykalova, A. A. Pavlychev, N. Kosugi, E. Rühl, Phys. Chem. Chem. Phys. 14 (2012) 9397.PubMedCrossrefGoogle Scholar

  • 43.

    R. Flesch, E. Seardarogu, X. O. Brykalova, E. I. Kan, E. S. Klyushina, Yu. S. Krivosenko, A. A. Pavlychev, E. Rühl, J. Chem. Phys. 138 (2013) 144302.PubMedCrossrefGoogle Scholar

  • 44.

    R. K. Lam, A. H. England, A. T. Sheardy, O. Shih, J. W. Smith, A. M. Rizzuto, D. Prendergast, R. J. Saykally, Chem. Phys. Lett. 614 (2014) 282.CrossrefGoogle Scholar

  • 45.

    S. G. Urquhart, H. Ade, J. Phys. Chem. B 106 (2002) 8531.Google Scholar

  • 46.

    M. L. Gordon, G. Cooper, C. Morin, T. Araki, C. C. Turci, K. Kaznatcheev, A. P. Hitchcock, J. Phys. Chem A 107 (2003) 6144.CrossrefGoogle Scholar

  • 47.

    E Otero, S. G. Urquhart, J. Phys. Chem A 110 (2006) 12121.CrossrefPubMedGoogle Scholar

  • 48.

    Y. Zubavichus, A. Shaporenko, M. Grunze, M. Zharnikov, J. Phys. Chem. B 110 (2006) 3420.PubMedCrossrefGoogle Scholar

  • 49.

    J. Stewart-Ornstein, A. P. Hitchcock, D. Hernàndez-Cruz, P. Henklein, J. Overhage, K. Hilpert, J. Hale, R. E. W. Hancock, J. Phys. Chem. B 111 (2007) 7691.PubMedCrossrefGoogle Scholar

  • 50.

    Y. Zubavichus, A. Shaporenko, M. Grunze, M. Zharnikov, J. Phys. Chem. A 109 (2005) 6998.CrossrefPubMedGoogle Scholar

  • 51.

    Y. Zubavichus, A. Shaporenko, M. L. Grunze, M. Zharnikov, J. Phys. Chem. B 112 (2008) 4478.PubMedCrossrefGoogle Scholar

  • 52.

    B. O. Leung, A. P. Hitchcock, J. L. Brash, A. Scholl, A. Doran, P. Henklein, J. Overhage, K. Hilpert, J. D. Hale, R. E. W. Hancock, Biointerphases 3 (2008) F27.CrossrefGoogle Scholar

  • 53.

    C. P. Schwartz, J. S. Uejio, A. M. Duffin, A. H. England, D. N. Kelly, D. Prendergast, R. J. Saykally, Proc. Nat. Acad. Sci. 107 (2010) 14008.CrossrefGoogle Scholar

  • 54.

    X. Liu, C. H. Jang, F. Zheng, A. Jürgensen, J. D. Denlinger, K. A. Dickson, R. T. Raines, N. L. Abbott, F. J. Himpsel, Langmuir 22 (2006) 7719.PubMedCrossrefGoogle Scholar

  • 55.

    J. S. Stevens, L. K. Newton, C. Jaye, C. A. Muryn, D. A. Fischer, S. L. M. Schroeder, Cryst. Growth Des. 15 (2015) 1776.CrossrefGoogle Scholar

  • 56.

    J. Wang, G. Cooper, D. Tulumello, A. P. Hitchcock, J. Phys. Chem. A 109 (2005) 10886.PubMedGoogle Scholar

  • 57.

    S. D. Perera, S. G. Urquhart, J. Phys. Chem A 121 (2017) 4907.CrossrefPubMedGoogle Scholar

  • 58.

    I. Ishii, A. P. Hitchcock, J. Chem. Phys. 87 (1987) 830.CrossrefGoogle Scholar

  • 59.

    D. A. Outka, J. Stohr, R. J. Madix, H. H. Rotermund, B. Hermsmeier, J. Solomon, Surf. Sci. 185 (1987) 53.CrossrefGoogle Scholar

  • 60.

    R. J. Jakobsen, Y. Mieawa, J. W. Brasch, Spectrochim. Acta A 23 (1967) 2199.CrossrefGoogle Scholar

  • 61.

    I. Ishii, A. P. Hitchcock, J. Electron Spectroscopy Rel. Phenom. 46 (1988) 55.CrossrefGoogle Scholar

  • 62.

    A. Ganesan, F. Wang, J. Chem. Phys. 131 (2009) 044321.CrossrefPubMedGoogle Scholar

  • 63.

    G. Olivieri, A. Cossaro, E. Capria, L. Benevoli, M. Coreno, M. De Simone, K. C. Prince, G. Kladnik, D. Cvetko, B. Fraboni, A. Morgante, L. Floreano, A. Fraleoni-Morgera, J. Phys. Chem. C 119 (2015) 121.CrossrefGoogle Scholar

  • 64.

    C. D. Cappa, J. D. Smith, W. R. Wilson, R. J. Saykally, J. Phys.: Condens. Matter 20 (2008) 205105.PubMedGoogle Scholar

  • 65.

    H. Bluhm, D. Frank Ogletree, C. S. Fadley, Z. Hussain, M. Salmeron, J. Phys. C 14 (2002) L221.Google Scholar

  • 66.

    I. Ishii, R. McLaren, A. P. Hitchcock, M. B. Robin, J. Chem. Phys. 87 (1987) 4344.CrossrefGoogle Scholar

  • 67.

    K. R. Wilson, B. S. Rude, T. Catalano, R. D. Schaller, J. G. Tobin, D. T. Co, R. J. Saykally, J. Phys. Chem. B 105 (2001) 3346.CrossrefGoogle Scholar

  • 68.

    A. Nilsson, D. Nordlund, I. Waluyo, N. Huang, H. Ogasawara, S. Kaya, U. Bergmann, L.-Å. Näslund, H. Öström, Ph. Wernet, K. J. Andersson, T. Schiros, L. G. M. Pettersson, J. Electron Spectroscopy Rel. Phenom. 177 (2010) 99.CrossrefGoogle Scholar

  • 69.

    I. Hjelte, M. N. Piancastelli, R. Fink, Reinhold, O. Björneholm, M. Bässler, R. Feifel, A. Giertz, K. Wiesner, A. Ausmees, C. Miron, Catalin, H. Wang, S. Sorensen, S. Svensson, Chem. Phys. Lett. 334 (2001) 151.CrossrefGoogle Scholar

  • 70.

    B. Brena, D. Nordlund, M. Odelius, H. Ogasawara, A. Nilsson, L. G. M. Pettersson, Phys. Rev. Lett. 93 (2004) 148302.PubMedCrossrefGoogle Scholar

  • 71.

    C. J. Sahle, J. Niskanen, K. Gilmore, S. Jahn, J. Electron Spectroscopy Rel. Phenom. (2017) in press. doi: 10.1016/j.elspec.2017.09.003.Google Scholar

  • 72.

    C. J. Sahle, C. Sternemann, S. Schmidt, S. Lehtola, S. Jahn, S. Simonelli, S. Huotari, M. Hakala, T. Pylkkänen, A. Nyrow, K. Mende, M. Tolan, K. Hämäläinen, M. Wilke, Proc. Nat. Acad. Sci. 110 (2013) 6301.CrossrefGoogle Scholar

About the article

aIssue in honor of Professor Eckart Rühl


Received: 2017-10-20

Accepted: 2017-10-28

Published Online: 2017-12-09

Published in Print: 2018-05-24


Citation Information: Zeitschrift für Physikalische Chemie, Volume 232, Issue 5-6, Pages 723–745, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2017-1061.

Export Citation

©2018 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Comments (0)

Please log in or register to comment.
Log in