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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus

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Volume 232, Issue 7-8

Issues

Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes

Bharti Kumari
  • Eduard-Zintl Institute for Inorganic and Physical Chemistry, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
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/ Daniel John
  • Ernst-Berl Institute for Chemical Engineering and Macromolecular Science, Technische Universität Darmstadt, Alarich-Weiss-Str. 4, D-64287 Darmstadt, Germany
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/ Paul Hoffmann
  • GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstr. 1, D-64291 Darmstadt, Germany
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/ Anne Spende
  • GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstr. 1, D-64291 Darmstadt, Germany
  • Materialwissenschaft, Technische Universität Darmstadt, Alarich-Weiss-Str. 2, D-64287 Darmstadt, Germany
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/ Maria Eugenia Toimil-Molares
  • Materialwissenschaft, Technische Universität Darmstadt, Alarich-Weiss-Str. 2, D-64287 Darmstadt, Germany
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/ Christina Trautmann
  • GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstr. 1, D-64291 Darmstadt, Germany
  • Materialwissenschaft, Technische Universität Darmstadt, Alarich-Weiss-Str. 2, D-64287 Darmstadt, Germany
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/ Christian Hess
  • Eduard-Zintl Institute for Inorganic and Physical Chemistry, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
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/ Philip Ruff
  • Eduard-Zintl Institute for Inorganic and Physical Chemistry, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
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/ Marcus Schulze
  • Physics of Surfaces, Institute of Materials Science and Center of Smart Interfaces, Technische Universität Darmstadt, Alarich-Weiss-Str. 16, D-64287 Darmstadt, Germany
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/ Robert Stark
  • Physics of Surfaces, Institute of Materials Science and Center of Smart Interfaces, Technische Universität Darmstadt, Alarich-Weiss-Str. 16, D-64287 Darmstadt, Germany
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/ Gerd Buntkowsky
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  • Eduard-Zintl Institute for Inorganic and Physical Chemistry, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, D-64287 Darmstadt, Germany
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/ Annette Andrieu-Brunsen
  • Ernst-Berl Institute for Chemical Engineering and Macromolecular Science, Technische Universität Darmstadt, Alarich-Weiss-Str. 4, D-64287 Darmstadt, Germany
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/ Torsten Gutmann
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Published Online: 2018-03-06 | DOI: https://doi.org/10.1515/zpch-2017-1032

Abstract

Surface enhanced solid-state NMR by dynamic nuclear polarization (DNP SENS) enables the characterization of the inner-pore surface functionalization of porous etched ion-track membranes exhibiting low specific surface areas compared to typical SBA- or MCM-type mesoporous silica materials. The membranes were conformally coated with a 5 nm thin SiO2 layer by atomic layer deposition. This layer was subsequently modified by aminopropyl silane linkers that allow further functionalization via the terminal amine group. The results evidence that in principle DNP SENS is a capable tool to analyze more complex porous systems, e.g. bioinspired functional etched ion-track membranes down to the molecular level. These results are relevant also for single nanopore systems, for which a direct analysis of the channel surface functionalization is not feasible by classical characterization methods. The applicability of DNP SENS to complex porous systems requires the optimization of the sample preparation and measurement parameters.

This article offers supplementary material which is provided at the end of the article.

Keywords: dynamic nuclear polarization; etched ion-track membranes; silica coating; solid-state NMR; surface analysis

References

  • 1.

    Z. Ezzeddine, I. Batonneau-Gener, Y. Pouilloux, H. Hamad, Z. Saad, V. Kazpard, Microporous Mesoporous Mater. 212 (2015) 125.CrossrefGoogle Scholar

  • 2.

    Q. Wen, D. Yan, F. Liu, M. Wang, Y. Ling, P. Wang, P. Kluth, D. Schauries, C. Trautmann, P. Apel, W. Guo, G. Xiao, J. Liu, J. Xue, Y. Wang, Adv. Funct. Mater. 26 (2016) 5796.CrossrefGoogle Scholar

  • 3.

    J. Duan, J. Liu, Y. Zhang, C. Trautmann, D. Y. Lei, J. Mater. Chem. C 4 (2016) 3956.Google Scholar

  • 4.

    I. Schubert, L. Burr, C. Trautmann, M. E. Toimil-Molares, Beilstein J. Nanotechnol. 6 (2015) 1272.PubMedCrossrefGoogle Scholar

  • 5.

    G. Pérez-Mitta, C. Trautmann, M. E. Toimil-Molares, O. Azzaroni, Single Ion Track-Etched Nanochannels for Analytical Applications, in “Chemically Modified Nanopores and Nanochannels” (Eds. M. Tagliazucchi, I. Szleifer), William Andrew, Elsevier (2016), P. 61.Google Scholar

  • 6.

    R. Spohr, Vol. Patent DE 2951376 C2, Germany (1979).Google Scholar

  • 7.

    A. Mara, Z. Siwy, C. Trautmann, J. Wan, F. Kamme, Nano Lett. 4 (2004) 497.CrossrefGoogle Scholar

  • 8.

    I. Vlassiouk, T. R. Kozel, Z. S. Siwy, J. Am. Chem. Soc. 131 (2009) 8211.CrossrefPubMedGoogle Scholar

  • 9.

    K. Healy, B. Schiedt, A. P. Morrison, Nanomedicine 2 (2007) 875.CrossrefGoogle Scholar

  • 10.

    R. L. Fleischer, P. B. Price, R. M. Walker, Nuclear Tracks in Solids: Principles and Applications, University of California Press, Berkeley (1975).Google Scholar

  • 11.

    A. Spende, N. Sobel, M. Lukas, R. Zierold, J. C. Riedl, L. Gura, I. Schubert, J. M. M. Moreno, K. Nielsch, B. Stuehn, C. Hess, C. Trautmann, M. E. Toimil-Molares, Nanotechnology 26 (2015) 335301.CrossrefPubMedGoogle Scholar

  • 12.

    N. Sobel, C. Hess, M. Lukas, A. Spende, B. Stühn, M. E. Toimil-Molares, C. Trautmann, Beilstein J. Nanotechnol. 6 (2015) 472.CrossrefPubMedGoogle Scholar

  • 13.

    J. Blümel, Coord. Chem. Rev. 252 (2008) 2410.CrossrefGoogle Scholar

  • 14.

    J. R. Rapp, Y. Huang, M. Natella, Y. Cai, V. S. Y. Lin, M. Pruski, Solid State Nucl. Mag. Res. 35 (2009) 82.CrossrefGoogle Scholar

  • 15.

    J. W. Wiench, Y. S. Avadhut, N. Maity, S. Bhaduri, G. K. Lahiri, M. Pruski, S. Ganapathy, J. Phys. Chem. B 111 (2007) 3877.PubMedCrossrefGoogle Scholar

  • 16.

    T. Gutmann, A. Grünberg, N. Rothermel, M. Werner, M. Srour, S. Abdulhussain, S. Tan, Y. Xu, H. Breitzke, G. Buntkowsky, Solid State Nucl. Mag. Res. 55 (2013) 1.Google Scholar

  • 17.

    M. Geppi, S. Borsacchi, G. Mollica, C. A. Veracini, Appl. Spectrosc. Rev. 44 (2009) 1.Google Scholar

  • 18.

    H. Koller, M. Weiss, Solid State NMR of Porous Materials Zeolites and Related Materials, in “Solid State NMR”, (Ed. J. C. C. Chan), Springer-Verlag, Berlin, Heidelberg, Vol. 306 (2012), P. 189–227.Google Scholar

  • 19.

    A. Lesage, M. Lelli, D. Gajan, M. A. Caporini, V. Vitzthum, P. Miéville, J. Alauzun, A. Roussey, C. Thieuleux, A. Medhi, G. Bodenhausen, C. Copéret, L. Emsley, J. Am. Chem. Soc. 132 (2010) 15459.PubMedCrossrefGoogle Scholar

  • 20.

    R. G. Griffin, Nature 468 (2010) 381.CrossrefPubMedGoogle Scholar

  • 21.

    M. Werner, A. Heil, N. Rothermel, H. Breitzke, P. B. Groszewicz, A. S. Thankamony, T. Gutmann, G. Buntkowsky, Solid State Nucl. Magn. Reson. 72 (2015) 73.CrossrefPubMedGoogle Scholar

  • 22.

    A. J. Rossini, A. Zagdoun, M. Lelli, A. Lesage, C. Copéret, L. Emsley, Acc. Chem. Res. 46 (2013) 1942.CrossrefPubMedGoogle Scholar

  • 23.

    M. Lelli, D. Gajan, A. Lesage, M. A. Caporini, V. Vitzthum, P. Miéville, F. Héroguel, F. Rascón, A. Roussey, C. Thieuleux, M. Boualleg, L. Veyre, G. Bodenhausen, C. Coperet, L. Emsley, J. Am. Chem. Soc. 133 (2011) 2104.CrossrefPubMedGoogle Scholar

  • 24.

    W. R. Gruening, A. J. Rossini, A. Zagdoun, D. Gajan, A. Lesage, L. Emsley, C. Coperet, Phys. Chem. Chem. Phys. 15 (2013) 13270.PubMedCrossrefGoogle Scholar

  • 25.

    A. Zagdoun, G. Casano, O. Ouari, G. Lapadula, A. J. Rossini, M. Lelli, M. Baffert, D. Gajan, L. Veyre, W. E. Maas, M. Rosay, R. T. Weber, C. Thieuleux, C. Coperet, A. Lesage, P. Tordo, L. Emsley, J. Am. Chem. Soc. 134 (2012) 2284.CrossrefPubMedGoogle Scholar

  • 26.

    T. Kobayashi, O. Lafon, A. S. Lilly Thankamony, I. I. Slowing, K. Kandel, D. Carnevale, V. Vitzthum, H. Vezin, J.-P. Amoureux, G. Bodenhausen, M. Pruski, Phys. Chem. Chem. Phys. 15 (2013) 5553.CrossrefPubMedGoogle Scholar

  • 27.

    E. Pump, J. Viger-Gravel, E. Abou-Hamad, M. K. Samantaray, B. Hamzaoui, A. Gurinov, D. H. Anjum, D. Gajan, A. Lesage, A. Bendjeriou-Sedjerari, L. Emsley, J. M. Basset, Chem. Sci. 8 (2017) 284.PubMedCrossrefGoogle Scholar

  • 28.

    M. P. Conley, R. M. Drost, M. Baffert, D. Gajan, C. Elsevier, W. T. Franks, H. Oschkinat, L. Veyre, A. Zagdoun, A. Rossini, M. Lelli, A. Lesage, G. Casano, O. Ouari, P. Tordo, L. Emsley, C. Coperet, C. Thieuleux, Chem. Eur. J. 19 (2013) 12234.CrossrefGoogle Scholar

  • 29.

    T. Gutmann, J. Liu, N. Rothermel, Y. Xu, E. Jaumann, M. Werner, H. Breitzke, S. T. Sigurdsson, G. Buntkowsky, Chem. Eur. J. 21 (2015) 3798.CrossrefGoogle Scholar

  • 30.

    A. Zagdoun, A. J. Rossini, M. P. Conley, W. R. Gruening, M. Schwarzwalder, M. Lelli, W. T. Franks, H. Oschkinat, C. Coperet, L. Emsley, A. Lesage, Angew. Chem. Int. Ed. 52 (2013) 1222.CrossrefGoogle Scholar

  • 31.

    A. R. Mouat, T. Kobayashi, M. Pruski, T. J. Marks, P. C. Stair, J. Phys. Chem. C 121 (2017) 6060.CrossrefGoogle Scholar

  • 32.

    A. J. Rossini, A. Zagdoun, M. Lelli, D. Gajan, F. Rascon, M. Rosay, W. E. Maas, C. Coperet, A. Lesage, L. Emsley, Chem. Sci. 3 (2012) 108.CrossrefGoogle Scholar

  • 33.

    O. Lafon, A. S. L. Thankamony, T. Kobayashi, D. Carnevale, V. Vitzthum, I. I. Slowing, K. Kandel, H. Vezin, J.-P. Amoureux, G. Bodenhausen, M. Pruski, J. Phys. Chem. C 117 (2013) 1375.CrossrefGoogle Scholar

  • 34.

    D. Lee, G. Monin, N. T. Duong, I. Z. Lopez, M. Bardet, V. Mareau, L. Gonon, G. De Paepe, J. Am. Chem. Soc. 136 (2014) 13781.PubMedCrossrefGoogle Scholar

  • 35.

    U. Akbey, B. Altin, A. Linden, S. Ozcelik, M. Gradzielski, H. Oschkinat, Phys. Chem. Chem. Phys. 15 (2013) 20706.PubMedCrossrefGoogle Scholar

  • 36.

    D. Gajan, M. Schwarzwälder, M. P. Conley, W. R. Gruning, A. J. Rossini, A. Zagdoun, M. Lelli, M. Yulikov, G. Jeschke, C. Sauvee, O. Ouari, P. Tordo, L. Veyre, A. Lesage, C. Thieuleux, L. Emsley, C. Coperet, J. Am. Chem. Soc. 135 (2013) 15459.PubMedCrossrefGoogle Scholar

  • 37.

    A. S. L. Thankamony, O. Lafon, X. Y. Lu, F. Aussenac, M. Rosay, J. Trebosc, H. Vezin, J. P. Amoureux, Appl. Magn. Reson. 43 (2013) 237.Google Scholar

  • 38.

    G. S. Foo, J. J. Lee, C. H. Chen, S. E. Hayes, C. Sievers, C. W. Jones, ChemSusChem 10 (2017) 266.PubMedCrossrefGoogle Scholar

  • 39.

    E. Ravera, V. K. Michaelis, T. C. Ong, E. G. Keeler, T. Martelli, M. Fragai, R. G. Griffin, C. Luchinat, Chemphyschem 16 (2015) 2751.PubMedCrossrefGoogle Scholar

  • 40.

    T. Kobayashi, D. Singappuli-Arachchige, Z. R. Wang, Slowing, II, M. Pruski, Phys. Chem. Chem. Phys. 19 (2017) 1781.PubMedCrossrefGoogle Scholar

  • 41.

    J. Q. Liu, P. B. Groszewicz, Q. B. Wen, A. S. L. Thankamony, B. Zhang, U. Kunz, G. Sauer, Y. P. Xu, T. Gutmann, G. Buntkowsky, J. Phys. Chem. C 121 (2017) 17409.CrossrefGoogle Scholar

  • 42.

    T. Gutmann, B. Kumari, L. Zhao, H. Breitzke, S. Schöttner, C. Rüttiger, M. Gallei, J. Phys. Chem. C 121 (2017) 3896.CrossrefGoogle Scholar

  • 43.

    G. Mollica, D. Le, F. Ziarelli, G. Casano, O. Ouari, T. N. T. Phan, F. Aussenac, P. Thureau, D. Gigmes, P. Tordo, S. Viel, ACS Macro Lett. 3 (2014) 922.CrossrefGoogle Scholar

  • 44.

    P. V. Der Voort, E. F. Vansant, J. Liq. Chromatogr. Relat. Technol. 19 (1996) 2723.CrossrefGoogle Scholar

  • 45.

    A. Spende, PhD Thesis, TU Darmstadt (2016).Google Scholar

  • 46.

    M. F. P. Wagner, F. Völklein, H. Reith, C. Trautmann, M. E. Toimil-Molares, Phys. Status Solidi B 213 (2016) 610.CrossrefGoogle Scholar

  • 47.

    I. Scholz, P. Hodgkinson, B. H. Meier, M. Ernst, J. Chem. Phys. 130 (2009) 114510.PubMedCrossrefGoogle Scholar

  • 48.

    A. E. Bennett, C. M. Rienstra, M. Auger, K. V. Lakshmi, R. G. Griffin, J. Chem. Phys. 103 (1995) 6951.CrossrefGoogle Scholar

  • 49.

    A. Grünberg, X. Yeping, H. Breitzke, G. Buntkowsky, Chem. Eur. J. 16 (2010) 6993.CrossrefGoogle Scholar

  • 50.

    K. Albert, R. Brindle, J. Schmid, B. Buszewski, E. Bayer, Chromatographia 38 (1994) 283.CrossrefGoogle Scholar

About the article

aBharti Kumari and Daniel John: These authors contributed equally to this work.


Received: 2017-09-08

Accepted: 2018-02-14

Published Online: 2018-03-06

Published in Print: 2018-07-26


Citation Information: Zeitschrift für Physikalische Chemie, Volume 232, Issue 7-8, Pages 1173–1186, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2017-1032.

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