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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) January 10, 2018

Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions

  • Martin Brodrecht , Bharti Kumari , Hergen Breitzke , Torsten Gutmann and Gerd Buntkowsky EMAIL logo

Abstract

A series of novel functionalized mesoporous silica-based materials with well-defined pore diameters, surface functionalization and surface morphology is synthesized by co-condensation or grafting techniques and characterized by solid-state NMR spectroscopy, DNP enhanced solid state-NMR and thermodynamic techniques. These materials are employed as host-systems for small-guest molecules like water, small alcohols, carbonic acids, small aromatic molecules, binary mixtures and others. The phase-behavior of these confined guests is studied by combinations of one dimensional solid-state NMR techniques (1H MAS, 2H-line shape analysis, 13C CPMAS) and two-dimensional correlation experiments like 1H-29Si- solid-state HETCOR.

Acknowledgements

Financial support by the Deutsche Forschungsgemeinschaft DFG in the frame-work of the special research unit FOR 1583 under contract Bu-911-18-1/2 is gratefully acknowledged.

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Received: 2017-10-20
Accepted: 2017-12-07
Published Online: 2018-01-10
Published in Print: 2018-07-26

©2018 Walter de Gruyter GmbH, Berlin/Boston

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