Abstract
A series of novel functionalized mesoporous silica-based materials with well-defined pore diameters, surface functionalization and surface morphology is synthesized by co-condensation or grafting techniques and characterized by solid-state NMR spectroscopy, DNP enhanced solid state-NMR and thermodynamic techniques. These materials are employed as host-systems for small-guest molecules like water, small alcohols, carbonic acids, small aromatic molecules, binary mixtures and others. The phase-behavior of these confined guests is studied by combinations of one dimensional solid-state NMR techniques (1H MAS, 2H-line shape analysis, 13C CPMAS) and two-dimensional correlation experiments like 1H-29Si- solid-state HETCOR.
Acknowledgements
Financial support by the Deutsche Forschungsgemeinschaft DFG in the frame-work of the special research unit FOR 1583 under contract Bu-911-18-1/2 is gratefully acknowledged.
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