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Zeitschrift für Physikalische Chemie

International journal of research in physical chemistry and chemical physics

Editor-in-Chief: Rademann, Klaus


IMPACT FACTOR 2017: 1.144
5-year IMPACT FACTOR: 1.144

CiteScore 2017: 1.08

SCImago Journal Rank (SJR) 2017: 0.495
Source Normalized Impact per Paper (SNIP) 2017: 0.495

Online
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2196-7156
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Volume 232, Issue 9-11

Issues

Gelation-Assisted Layer-by-Layer Deposition of High Performance Nanocomposites

Jian Zhu / Douglas Watts / Nicholas A. Kotov
  • Corresponding author
  • Department of Chemical Engineering, University of Michigan, Ann Arbor 48109, USA
  • Department of Materials Science and Engineering, University of Michigan, Ann Arbor 48109, USA
  • Department of Biomedical Engineering, University of Michigan, Ann Arbor 48109, USA
  • BioInterface Institute, University of Michigan, Ann Arbor 48109, USA
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Published Online: 2018-07-18 | DOI: https://doi.org/10.1515/zpch-2018-1169

Abstract

Layer-by-layer (LBL) assembly produces nanocomposites with distinctively high volume fractions of nanomaterials and nanometer scale controlled uniformity. Although deposition of one nanometer scale layer at a time leads to high performance composites, this deposition mode is also associated with the slow multilayer build-up. Exponential LBL, spin coating, turbo-LBL and other methods tremendously accelerate the multilayer build-up but often yield lower, strength, toughness, conductivity, etc. Here, we introduce gelation assisted layer-by-layer (gaLBL) deposition taking advantage of a repeating cycle of hydrogel formation and subsequent polymer infiltration demonstrated using aramid nanofiber (ANF) and epoxy resin (EPX) as deposition partners. Utilization of ANF gels increases the thickness of each deposited layer from 1–10 nm to 30–300 nm while retaining fine control of thickness in each layer, high volume fraction, and uniformity. While increasing the speed of the deposition, the high density of interfaces associated with nanofiber gels helps retain high mechanical properties. The ANF/EPX multilayer composites revealed a rare combination of properties that was unavailable in traditional aramid-based and other composites, namely, high ultimate strength of 505±47 MPa, high toughness of 50.1±9.8 MJ/m3, and high transparency. Interestingly, the composite also displayed close-to-zero thermal expansion. The constellation of these materials properties is unique both for quasi-anisotropic composites and unidirectional materials with nanofiber alignment. gaLBL demonstrates the capability to resolve the fundamental challenge between high-performance and scalability. The gelation-assisted layered deposition can be extended to other functional components including nanoparticle gels.

This article offers supplementary material which is provided at the end of the article.

Keywords: bioinspired materials; coefficient of thermal expansion; hierarchical materials; hybrid materials; layer-by-layer assembly; nanocomposite; nanofiber; nanostructured gels; property correlation; strength; toughness; transparency

References

About the article

Received: 2018-02-28

Accepted: 2018-04-16

Published Online: 2018-07-18

Published in Print: 2018-08-28


Citation Information: Zeitschrift für Physikalische Chemie, Volume 232, Issue 9-11, Pages 1383–1398, ISSN (Online) 2196-7156, ISSN (Print) 0942-9352, DOI: https://doi.org/10.1515/zpch-2018-1169.

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[1]
Nadja C. Bigall and Nikolai Gaponik
Zeitschrift für Physikalische Chemie, 2018, Volume 232, Number 9-11, Page 1263

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