Comparative studies of Pd, Ru, Ni, Cu/ZnAl2O4 catalysts for the water gas shift reaction

Pawel Mierczynski 1 , Waldemar Maniukiewicz 1 , and Tomasz Maniecki 1
  • 1 Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924, Łódź, Poland

Abstract

The activity of monometallic Pd, Ru, Ni and Cu catalysts supported on spinel ZnAl2O4 for water gas shift reaction (WGS) was investigated. The physicochemical properties of each catalyst was studied by XRD, TPR, BET and chemisorption methods. The highest activity was obtained for Cu/ZnAl2O4 among the catalysts tested. The activation process carried out in a reducing atmosphere 5%H2-95%Ar in the case of Cu/ZnAl2O4 system lead to the catalytic activity improvement. In the case of copper catalysts, the water gas shift reaction proceeded by the redox surface mechanism between Cu0/Cu+. The PdZn alloy formation after reduction at 350°C was shown.

If the inline PDF is not rendering correctly, you can download the PDF file here.

  • [1] L. Lloyd, D.E. Ridler, M.V. Twigg, Catalyst Handbook (Manson Publ. Ltd., London, 1996)

  • [2] K. Kochloefl, “Steam reforming” in Handbook of Heterogeneous Catalysis (VCH, Weinheim, 1997) 4, 1819

  • [3] L. Bollmann, J.L. Ratts, A.M. Joshi, W.D. Williams, J. Pazmino, Y.V. Joshi, J.T. Miller, A.J. Kropf, W.N. Delgass, F.H. Ribeiro, J. Catal. 257, 96 (2008) http://dx.doi.org/10.1016/j.jcat.2008.04.005

  • [4] C.H. Bartholomew, J.F. Farrauto Fundamentals of Industrial Catalytic Processes (Wiley Interscience, New York, 2006)

  • [5] B.B. Pearce, M.V. Twigg, C. Woodward Catalyst Handbook, 2nd edition (Manson Publ. Ltd., London, 1996)

  • [6] A.F. Ghenciu, Current Opinion in Solid State and Materials Science 6, 389 (2002)

  • [7] N. Hua, H. Wang, Y. Du, M. Shen, P. Yang, Catal. Commun. 6, 491 (2005) http://dx.doi.org/10.1016/j.catcom.2005.04.014

  • [8] R.J. Gorte, S. Zhao, Catal. Today 104, 18 (2005) http://dx.doi.org/10.1016/j.cattod.2005.03.034

  • [9] Y. Li, Q. Fu, M.F. Stephanopoulos, Appl Catal B 27, 179 (2000) http://dx.doi.org/10.1016/S0926-3373(00)00147-8

  • [10] S.H. Kim, S.W. Nam, H.I. Lee, Appl. Catal. B 81, 97 (2008) http://dx.doi.org/10.1016/j.apcatb.2007.12.009

  • [11] A.S. Korotkov, N.M. Alexandrov, Comput. Mater. Sci. 35, 442 (2006) http://dx.doi.org/10.1016/j.commatsci.2005.02.012

  • [12] P. Mierczynski, T.P. Maniecki, K. Chalupka, W. Maniukiewicz, W.K. Jozwiak, Catal. Today 176, 21 (2011) http://dx.doi.org/10.1016/j.cattod.2011.06.009

  • [13] M.N. Barroso, M.F. Gomez, J.A. Gamboa, L.A. Arrua, M.C. Abello, J. Phys. Chem. Solids 67,1583 (2006) http://dx.doi.org/10.1016/j.jpcs.2006.01.114

  • [14] M.L. Cubeiro, J.L.G. Fierro, J. Catal. 179, 150 (1998) http://dx.doi.org/10.1006/jcat.1998.2184

  • [15] A. Karim, T. Conant, A. Datye, J. Catal. 243, 420 (2006) http://dx.doi.org/10.1016/j.jcat.2006.07.024

  • [16] B. Lindström, L.J. Pettersson, P.G. Menon, Appl. Catal. A 234, 111 (2002) http://dx.doi.org/10.1016/S0926-860X(02)00202-8

  • [17] M. Turco, G. Bagnasco, U. Constantino, F. Marmottini, T. Montanari, G. Raims, G. Busca, J. Catal. 228, 43 (2004)

  • [18] Ching-Huei Wang, Chemosphere 55, 11 (2004) http://dx.doi.org/10.1016/j.chemosphere.2003.10.036

  • [19] H. Muroyama, R. Nakase, T. Matsui, K. Eguchi, Int. J. Hydrogen Energy 35, 1575 (2010) http://dx.doi.org/10.1016/j.ijhydene.2009.12.083

  • [20] T.P. Maniecki, K. Bawolak-Olczak, P. Mierczynski, W. Maniukiewicz, W.K. Jozwiak, Chem. Eng. J. 154, 142 (2009) http://dx.doi.org/10.1016/j.cej.2009.05.007

  • [21] Lee Jae-Hee, Lee Eun-Gu, Joo Oh-Shim, Jung Kwang-Deog, Appl. Catal. A: Gen. 269, 1 (2004) http://dx.doi.org/10.1016/j.apcata.2004.01.035

  • [22] M. Nurunnabi, K. Murata, K. Okabe, M. Inaba, I. Takahara, Catal. Commun. 8, 1531 (2007) http://dx.doi.org/10.1016/j.catcom.2007.01.008

  • [23] G. Ertl, R. Hier, H. Knozinger, N. Thiele, H.P. Urbach, Applications of Surface Science 5, 49 (1980) http://dx.doi.org/10.1016/0378-5963(80)90117-8

  • [24] M. Yin, Ch.-K. Wu, Y. Lou, C. Burda, J.T. Koberstein, Y. Zhu, S. O’Brien, J. Am. Chem. Soc. 127, 9506 (2005) http://dx.doi.org/10.1021/ja050006u

  • [25] Y. Li, Q. Fu, M. Flytzani-Stephanopoulos, Appl. Catal. B 27, 179 (2000) http://dx.doi.org/10.1016/S0926-3373(00)00147-8

  • [26] N.A. Koryabkina, A.A. Phatak, W.F. Ruettinger, R.J. Farrauto, F.H. Ribeiro, J. Catal. 217, 233 (2003)

  • [27] T. VanHerwijnen, W.A. DeJong, J. Catal. 63, 83 (1980) http://dx.doi.org/10.1016/0021-9517(80)90061-5

  • [28] D.C. Grenoble, M.M. Estadt, D.F. Ollis, J. Catal. 67, 90 (1981) http://dx.doi.org/10.1016/0021-9517(81)90263-3

  • [29] T. Salmi, R. Hakkarainen,Appl. Catal. 49, 285 (1989) http://dx.doi.org/10.1016/S0166-9834(00)83024-9

  • [30] K. Takanabe, K. Aika, K. Seshan, L. Lefferts, J. Catal. 227, 101 (2004) http://dx.doi.org/10.1016/j.jcat.2004.07.002

  • [31] D. Andreeva, I. Ivanov, L. Ilieva, J.W. Sobczak, G. Avdeev, K. Petrov, Topics in Catalysis 44, 173 (2007) http://dx.doi.org/10.1007/s11244-007-0291-y

  • [32] K.G. Azzam, I.V. Babich, K. Seshan, L. Lefferts, J. Catal. 251, 153 (2007) http://dx.doi.org/10.1016/j.jcat.2007.07.010

  • [33] G. Jacobs, U.M. Graham, E. Chenu, P.M. Patterson, A. Dozier, B.H. Davis, J. Catal. 229, 499 (2005) http://dx.doi.org/10.1016/j.jcat.2004.11.031

  • [34] A. Goguet, S.O. Shekhtman, R. Burch, C. Hardcare, F.C. Meunier, G.S. Yablonsky, J. Catal. 237, 102 (2006) http://dx.doi.org/10.1016/j.jcat.2005.10.020

  • [35] S.Y. Choung, M. Ferrandon, T. Krause, Catal. Today 99, 257 (2005) http://dx.doi.org/10.1016/j.cattod.2004.10.002

  • [36] Y. Sekine, H. Takamatsu, S. Aramaki, K. Ichishima, M. Takada, M. Matsukata, E. Kikuchi, Appl. Catal. A: Gen. 352, 214 (2009) http://dx.doi.org/10.1016/j.apcata.2008.10.008

  • [37] S. Hilaire, X. Wang, T. Luo, R.J. Gorte, J. Wagner, Appl. Catal. A: Gen. 215, 271 (2001) http://dx.doi.org/10.1016/S0926-860X(01)00535-X

  • [38] T. Bunluesin, R.J. Gorte, G.W. Graham, Appl. Catal. B, 15,107 (1998) http://dx.doi.org/10.1016/S0926-3373(97)00040-4

  • [39] K.G. Azzam, I.V. Babich, K. Seshan, L. Lefferts, Appl. Catal. B 80,129 (2008) http://dx.doi.org/10.1016/j.apcatb.2007.11.015

  • [40] T.P. Maniecki, P. Mierczynski, W.K. Jozwiak, Kinet. Catal. 51, 843 (2010) http://dx.doi.org/10.1134/S0023158410060108

  • [41] Ch. Vignatti, M.S. Avila, C.R. Apesteguia, T.F. Garetto, Int. J. Hydrogen Energy 35, 7302 (2010) http://dx.doi.org/10.1016/j.ijhydene.2010.04.180

  • [42] M.J.L. Ginès, N. Amadeo, M. Laborde, C.R. Apesteguìa, Appl. Catal. A: Gen. 131, 283 (1995) http://dx.doi.org/10.1016/0926-860X(95)00146-8

OPEN ACCESS

Journal + Issues

Search