Hydrogen sorption characteristics of magnesium-based composites with addition of Mg2Ni0.7Co0.3 and graphite

E. Grigorova 1 , M. Khristov 1 , and M. Khrussanova 1
  • 1 Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria

Abstract

Magnesium-based composites of 75 wt% Mg — (10, 15, 20) wt% Mg2Ni0.7Co0.3 — (15, 10, 5) wt% C mechanically activated for 30 min under argon in a planetary mill, were obtained. Their absorption-desorption characteristics were investigated under a pressure P = 1 MPa and temperatures of 623, 573, 473, 423 and 373 K. Desorption was carried out at 623 K and 573 K and a pressure of 0.15 MPa. All the three composites showed improved hydriding kinetics as compared to pure magnesium. However, the desorption temperature was somewhat higher than needed for practical application.

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  • [1] A. Zaluska, L. Zaluski, J.O. Ström-Olsen, J. Alloys Comp. 288, 217 (1999) http://dx.doi.org/10.1016/S0925-8388(99)00073-0

  • [2] J.J. Reilly, R.H. Wiswall, J. Inorg. Chem. 7, 2254 (1968) http://dx.doi.org/10.1021/ic50069a016

  • [3] Y. Ishido, S. Ono, E. Akiba, J. Less-Common Met. 120, 163 (1986) http://dx.doi.org/10.1016/0022-5088(86)90641-7

  • [4] G. Liang, S. Boily, J. Alloys Comp. 267, 302 (1998) http://dx.doi.org/10.1016/S0925-8388(97)00533-1

  • [5] H. Aoyagi, K. Aoki, T. Masumoto, J. Alloys Comp. 231, 804 (1995) http://dx.doi.org/10.1016/0925-8388(95)01721-6

  • [6] M. Abdellaoui, D. Cracco, A. Percheron-Guegan, J. Alloys Comp. 293–295, 501 (1999) http://dx.doi.org/10.1016/S0925-8388(99)00475-2

  • [7] K. Yamamoto, S. Orimo, H. Fujii, Y. Kitano, J. Alloys Comp. 293–295, 546 (1999) http://dx.doi.org/10.1016/S0925-8388(99)00409-0

  • [8] L. Li, T. Akiyama, J. Yagi, J. Alloys Comp. 316, 118 (2001) http://dx.doi.org/10.1016/S0925-8388(00)01286-X

  • [9] T. Spassov, P. Solsona, S. Bliznakov, S. Suriăch, M.D. Baró, J. Alloys Comp. 356–357, 639 (2003) http://dx.doi.org/10.1016/S0925-8388(03)00122-1

  • [10] E. Rönnebro, D. Noréus, Appl. Surf. Science 228, 115 (2004) http://dx.doi.org/10.1016/j.apsusc.2004.01.030

  • [11] H. Reule, M. Hirscher, A. Weiβhardt, H. Krönmuller, J. Alloys Comp. 305, 246 (2000) http://dx.doi.org/10.1016/S0925-8388(00)00710-6

  • [12] B. Sakintuna, F. Lamari-Darkrim, M. Hirscher, Int. J. Hydrogen Energy 32, 1121 (2007) http://dx.doi.org/10.1016/j.ijhydene.2006.11.022

  • [13] J.-L. Bobet, E. Grigorova, M. Khrussanova, M. Khristov, D. Radev, P. Peshev, J. Alloys Comp. 345, 280 (2002) http://dx.doi.org/10.1016/S0925-8388(02)00435-8

  • [14] M. Khrussanova, E. Grigorova, J.-L. Bobet, M. Khristov, P. Peshev, J. Alloys Comp. 365, 308 (2004) http://dx.doi.org/10.1016/S0925-8388(03)00684-4

  • [15] H. Imamura, N. Sakasai, Y. Kajii, J. Alloys Comp. 232, 218 (1996) http://dx.doi.org/10.1016/0925-8388(95)01882-4

  • [16] S. Nohara, H. Inoue, Y. Fukumoto, C. Iwakura, J. Alloys Comp. 252, L16 (1997) http://dx.doi.org/10.1016/S0925-8388(96)02675-8

  • [17] S. Bouaricha, J-P. Dodelet, D. Guay, J. Huot, R. Schulz, J. Mater. Res. 16, 2893 (2001) http://dx.doi.org/10.1557/JMR.2001.0398

  • [18] S. Bouaricha, J-P. Dodelet, D. Guay, J. Huot, R. Schulz, J. Alloys Comp. 307, 226 (2000) http://dx.doi.org/10.1016/S0925-8388(00)00804-5

  • [19] S. Bouaricha, J-P. Dodelet, D. Guay, J. Huot, R. Schulz, J. Alloys Comp. 325, 245 (2001) http://dx.doi.org/10.1016/S0925-8388(01)01390-1

  • [20] S. Ruggeri, L. Roué, G. Liang, J. Huot, R. Schulz, J. Alloys Comp. 343, 170 (2002) http://dx.doi.org/10.1016/S0925-8388(02)00207-4

  • [21] H. Imamura, S. Tabata, N. Shigetomi, Y. Takesue, Y. Sakata, J. Alloys Comp. 330–332, 579 (2002) http://dx.doi.org/10.1016/S0925-8388(01)01506-7

  • [22] J. Huot, M.-L. Tremblay, R. Schulz, J. Alloys Comp. 356–357, 603 (2003) http://dx.doi.org/10.1016/S0925-8388(03)00120-8

  • [23] H. Imamura et al., Acta Mater. 51, 6407 (2003) http://dx.doi.org/10.1016/j.actamat.2003.08.010

  • [24] J.-L. Bobet et al., J. Alloys Comp. 366, 298 (2004) http://dx.doi.org/10.1016/S0925-8388(03)00746-1

  • [25] C.X. Shang, Z.X. Guo, J. Power Sources 129, 73 (2004) http://dx.doi.org/10.1016/j.jpowsour.2003.11.013

  • [26] R. Janot, X. Darok, A Rougier, L. Aymard, G.A. Nazri, J.-M. Tarascon, J. Alloys Comp. 404–406, 293 (2005) http://dx.doi.org/10.1016/j.jallcom.2005.01.129

  • [27] B. Tanguy, JL. Soubeyroux, M. Pezat, J. Portier, P. Hagenmuller, Mater. Res. Bull. 11, 1441 (1976) http://dx.doi.org/10.1016/0025-5408(76)90057-X

  • [28] Z.G. Huang, Z.P. Guo, A. Calka, D. Wexler, H.K. Liu, J. Alloys Comp. 427, 94 (2007) http://dx.doi.org/10.1016/j.jallcom.2006.03.069

  • [29] C.Z. Wu et al., J. Alloys Comp. 414, 259 (2006) http://dx.doi.org/10.1016/j.jallcom.2005.07.021

  • [30] A.D. Rud et al., Int. J. Hydrogen Energy 33(4), 1310 (2008) http://dx.doi.org/10.1016/j.ijhydene.2007.12.032

  • [31] M. Khrussanova, M. Terzieva, P. Peshev, J. Less-Common Met. 125, 117 (1986) http://dx.doi.org/10.1016/0022-5088(86)90086-X

  • [32] E. Grigorova, M. Khristov, M. Khrussanova, J.-L. Bobet, P. Peshev, Int. J. Hydrogen Energy 30, 1099 (2005) http://dx.doi.org/10.1016/j.ijhydene.2004.10.018

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