A novel redox-active calix[4]arene-tetrathiafulvalene dyad

Bang-Tun Zhao 1 , Xiao-Min Zhu 2 , Qi-Ming Peng 2 , Zhen-Ning Yan 2 , Franck Derf 3 , and Marc Sallé 3
  • 1 Department of Chemistry, Luoyang Normal University, Luoyang, 471022, P. R. China
  • 2 Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, P. R. China
  • 3 Laboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, F-49045, Angers, France

Abstract

A novel redox-active calix[4]arene-TTF 5 was prepared by the reaction of p-tert-butylcalix[4]arene 4 with the tosylated TTF 3 in the presence of cesium fluoride. The structure of the dyad 5 was identified by X-ray diffraction analysis, and the preliminary electrochemical properties of 5 were investigated by cyclic voltammetry (CV), for which two reversible one-electron waves were observed. Moreover, the UV-vis absorption spectra studies show that the dyad 5 undergoes progressive oxidation at the TTF moiety in presence of increasing amounts of Cu2+ or Hg2+.

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