Modeling kraft cooking kinetics of fiber mixes from TMP and unbleached kraft pulps for assessment of old corrugated cardboard delignification

Lucas Dollié 1 , Gérard Mortha 1  and Nathalie Marlin 1
  • 1 Université Grenoble Alpes, CNRS, Grenoble INP, LGP2, F-38000 Grenoble, France
Lucas Dollié, Gérard Mortha and Nathalie Marlin

Abstract

Kraft cooking kinetics of three different lignocellulosic substrates have been investigated, namely fibers from unbleached kraft pulp (UBKP from Pinus radiata), fibers from softwood unbleached thermomechanical pulp (TMP), and wood chips for TMP production. UBKP and TMP were considered to be representative of a fiber mixture obtained after the pulping and cleaning of old corrugated cardboards (OCC). The characteristic parameters for fitting a mathematical model for kraft pulping were estimated. Based on the results, a “fiber mixture cooking model” was developed to predict the cooking kinetics of TMP/UBKP mixes, accounting for the proportion of each component. The aim was to tailor OCC upcycling in terms of high quality products, which can be used for various purposes including paper and non-paper applications.

  • Ackert, J.E., Koch, D.D., Edwards, L.L. (1975) Displacement chlorination of kraft pulps: I. An experimental study and comparison of models. TAPPI J. 58:141–145.

  • Adamopoulos, S., Martinez, E., Ramirez, D. (2007) Characterization of packaging grade papers from recycled raw materials through the study of fiber morphology and composition. Global NEST J. 9:20–28.

  • AFNOR standard (1981) NFT 12-005 var. A cellulose-determination of the maximum viscosity index of cellulose in diluted solutions.

  • Cho, H.J., Sarkanen, K.V. (1985) Alternatives to H. factor measurement in the kraft process. Pap. Puu 67:121–124.

  • Danielewicz, D., Surma-Ślusarska, B. (2015) Properties of bleached pulps from low and high kappa number old corrugated containers (OCC). Fibres Text. East. Eur. 5:129–135.

  • De Ruvo, A., Farnstrand, P.A., Hagen, N., Haglund, N. (1986) Upgrading of pulp from corrugated containers by oxygen delignification. TAPPI J. 69:100–103.

  • Economou, A.M., Economides, D., Vlyssides, A.G. (1997) Totally chlorine free bleaching of secondary fibers of low mechanical pulp content with the application of oxygen, ozone and in situ produced dimethyldioxirane. Prog. Pap. Recycl. 7:37–49.

  • Gustafson, R.R., Sleicher, C.A., McKean, W.T., Finlayson, B.A. (1983) Theoretical model of the kraft pulping process. Ind. Eng. Chem. Proc. DD. 22:87–96.

  • Hamzeh, Y., Izadyar, S., Mortha, G. (2007) Elemental chlorine free delignification of chemical pulp in flow through reactor. J. Appl. Sci. 7:3786–3790.

  • Jackson, M., Croon, I.L., Nardi, F. (1994) Bleached fiber from OCC. TAPPI J. 77:153–159.

  • Kihlman, M., Aldaeus, F., Chedid, F., Germgård, U. (2012) Effect of various pulp properties on the solubility of cellulose in sodium hydroxide solutions. Holzforschung 66:601–606.

  • Koç, B.O., Gümüşkaya, E., Erişir, E., Peşman, E., Kirci, H. (2017) Comparison of reinforced oxygen delignification methods for old corrugated board (OCC) fibers. Drewno  60:47–64.

  • Lapierre, L., Bouchard, J. (1997) Molecular weight determination of softwood kraft cellulose. Presented at the 9th ISWPC, Montreal, Canada: L6–1–L6–6.

  • Li, Z., Ni, I., Van Heiningen, A.R.P. (1996) Bleaching of mechanical pulps in a displacement system: interesting results were obtained. Pulp Pap. – Canada 97:46–50.

  • Ma, Y., Hummel, M., Määttänen, M., Särkilahti, A., Harlin, A., Sixta, H. (2016) Upcycling of waste paper and cardboard to textiles. Green Chem. 18:858–866.

  • Mortha, G., Jain, S. (2008) SFGP 2007 – modelling kraft cooking of wood species mixtures. Int. J. Chem. Reac. Eng. 6:2–5.

  • Nguyen, X.T., Simard, L. (1996) On the delignification of OCC with hydrogen peroxide. International Pulp Bleaching Conference, TAPPI Press, Washington, DC. pp. 569–577.

  • Östberg, L., Kvarnlöf, N., Germgård, U. (2013) The hemicellulose content in two chemical pulps and its influence on Fock’s test and the gamma number of the resulting viscose dope. Nordic Pulp Pap. Res. J. 28:377–380.

  • Peredo, K., Reyes, H., Escobar, D., Vega-Lara, J., Berg, A., Pereira, M. (2015) Acetylation of bleached kraft pulp: effect of xylan content on properties of acetylated compounds. Carbohyd. Polym. 117:1014–1020.

  • Rapson, W.H., Anderson, C.B. (1966) Dynamic bleaching: continuous movement of pulp through liquor increases bleaching rate. TAPPI 49:329–334.

  • Sihtola, H. (1963) Comparison and conversion of viscosity and DP values determined by different methods. Pap. Puu 45:225–323.

  • Sixta, H. (2006) Handbook of pulp. In: Pulp Properties and Applications, Ed. Sixta, H. Wiley-VCH, Weinheim. pp. 1036.

  • Sunyoung, L., McKean, W.T., Gustafson, R.R. (1996) Manufacture of Bleached Pulp from Recycled OCC Linerboard. Pulping Conference, Nashville. pp. 885–893.

  • TAPPI standard (2007) T 204. Cm-07, Solvent extractives of wood and pulp.

  • TAPPI standard (2011) T 222. Om-11, Acid-insoluble lignin in wood and pulp.

  • TAPPI standard (2012) T 211. Cm-12, Ash in wood, pulp, paper and paperboard: combustion at 525°C.

  • TAPPI standard (2013) T 210. Cm-13, Sampling and testing wood pulp shipments for moisture.

  • Vroom, K.E. (1957) The H factor: a means of expressing cooking times and temperatures as a single variable. Pulp Paper Mag. Can. 58:228–231.

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Holzforschung is an international scholarly journal that publishes cutting-edge research on the biology, chemistry, physics and technology of wood and wood components. High quality papers about biotechnology and tree genetics are also welcome. Rated year after year as one of the top scientific journals in the category of Pulp and Paper (ISI Journal Citation Index), Holzforschung represents innovative, high quality basic and applied research.

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