Nanostructured Organosilicon Luminophores for Effective Light Conversion in Organic Light Emitting Diodes

Yuriy N. Luponosov 1 , Nikolay M. Surin 1 , Diana K. Susarova 2 , Mikhail I. Buzin 3 , Denis V. Anokhin 4 , 5 , Dimitri A. Ivanov 4 , 5 , Pavel A. Troshin 2  and Sergei A. Ponomarenko 6 , 7
  • 1 Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya 70, Moscow 117393, Russia
  • 2 Institute of Problems of Chemical Physics of Russian Academy of Sciences, Russia
  • 3 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow, 119991, Russia
  • 4 Moscow State University, Faculty of Fundamental Physical and Chemical Engineering, GSP-1, 1-51 Leninskie Gory, Moscow, 119991, Russia
  • 5 Institut de Sciences des Matériaux de Mulhouse (CNRS UMR7361), 15 rue Jean Starcky, B.P 2488, Mulhouse, 68057, France
  • 6 Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya 70, Moscow 117393, Russia
  • 7 Moscow State University, Faculty of Chemistry, Leninskie gory, Moscow, 119992 Russia

Abstract

Full characterization of nanostructured organosilicon luminophores NOL4 and NOL5 based on the donor 2,2’-bithiophene and acceptor 1,4-bis(2,2′- bithiophene-5-yl)benzene units in dilute solutions and thin films by UV-Vis spectroscopy, DSC, TGA and X-ray techniques was reported. It was found that usage of these molecules as dopants (10–20 wt%) to the electroactive polyfluorene host in organic light-emitting devices (OLEDs) leads to the efficient spectral long wavelength shifting of the electroluminescence and an increase of the OLED performance as compared to the devices based on pristine polyfluorene, NOL4 and NOL5.

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