Lead acetate trihydrate crystallizes in a tetramolecular, monoclinic unit cell of dimensions a = 15.85(1), b = 7.30(1), c = 9.10(1) Å, β = 109.8(5)° in the space group C2/m. The crystal structure has been solved by the heavy-atom method and refined to an R value of 0.096 for 790 observed reflections. Nine oxygen atoms belonging to the water molecules and acetate groups coordinate the lead atom whose coordination polyhedron is a monocapped square antiprism. The two crystallographically different acetate groups coordinate both bidentally to the same metal atom. A hydrogen bonding scheme based on the distance criteria has been proposed.
Zeitschrift für Kristallographie – Crystalline Materials offers a place for researchers to present results of their crystallographic studies. The journal includes theoretical as well as experimental research. It publishes Original Papers, Letters and Review Articles in manifold areas of crystallography.
01 Jan 1877
Evgeny Antipov, Elena V. Boldyreva, Karen Friese, Hubert Huppertz, Sandro Jahn and E. R. T. Tiekink