The crystal structure of TlCr3S5: A redetermination

W. Bensch and E. Wörner

Abstract

TlCr3S5 crystallizes in the monoclinic space group C2/m with the lattice parameters a = 19.293(4), b = 3.4653(9), c = 11.962(2) Å, β = 122.18(3)°, V = 676.8(3) Å3, Z = 4. The structure was refined to R = 0.067 and Rw = 0.048. CrS6 octahedra are joined by common edges and faces leading to a three dimensional network with channels parallel to the crystallographic b-axis. The Tl atoms are confined within these channels.

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Zeitschrift für Kristallographie – Crystalline Materials offers a place for researchers to present results of their crystallographic studies. The journal includes theoretical as well as experimental research. It publishes Original Papers, Letters and Review Articles in manifold areas of crystallography.

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