Exit wave reconstruction from focal series of HRTEM images, single crystal XRD and total energy studies on SbxWO3+y (x ∼ 0.11)

Miia Klingstedt 1 , Margareta Sundberg, Lars Eriksson 2 , Sarah Haigh 3 , Angus Kirkland 4 , Daniel Grüner 5 , Annick De Backer 6 , Sandra Van Aert 7 , and Osamu Terasaki 8
  • 1  Stockholm University, Department of Materials and Environmental Chemistr, Stockholm, Schweden
  • 2  Stockholm University, Department of Materials and Environmental Chemistr, Stockholm, Schweden
  • 3  University of Manchester, Materials Science Centre, Manchester, Großbritannien
  • 4  University of Oxford, Department of Materials, Oxford, Großbritannien
  • 5  Max-Planck-Institut für Chemische Physik fester Stoffe, Dresden, Deutschland
  • 6  University of Antwerp (EMAT), Electron Microscopy for Materials Research, Antwerp, Belgien
  • 7  University of Antwerp (EMAT), Electron Microscopy for Materials Research, Antwerp, Belgien
  • 8  Stockholm University, Department of Materials and Environmental Chemistr, Stockholm, Schweden

Abstract

A new tungsten bronze in the Sb—W—O system has been prepared in a solid state reaction from Sb2O3, WO3 and W metal powder. The average structure was determined by single crystal X-ray diffraction. SbxWO3+y (x ∼ 0.11) crystallizes in the orthorhombic space group Pm21n (no. 31), a = 27.8135(9) Å, b = 7.3659(2) Å and c = 3.8672(1) Å. The structure belongs to the (n)-ITB class of intergrowth tungsten bronzes. It contains slabs of hexagonal channels formed by six WO6 octahedra. These slabs are separated by three layers of WO6 octahedra that are arranged in a WO3-type fashion. The WO6 octahedra share all vertices to build up a three-dimensional framework. The hexagonal channels are filled with Sb atoms to ∼80% and additional O atoms. The atoms are shifted out of the center of the channels. Exit-wave reconstruction of focal series of high resolution-transmission-electron-microscope (HRTEM) images combined with statistical paramäeter estimation techniques allowed to study local ordering in the channels. Sb atoms in neighbouring channels tend to be displaced in the same direction, which is in agreement with total energy calculations on ordered structure models, but the ratio of the occupation of the two possible Sb sites varies from channel to channel. The structure of SbxWO3+y exhibits pronounced local modulations.

    • Supplemental Material archive (ZIP)
Purchase article
Get instant unlimited access to the article.
$42.00
Log in
Already have access? Please log in.


or
Log in with your institution

Journal + Issues

Search