Application of a New Principle of Assignment to the Infrared Spectrum of 2-Chloroacrylonitrile

F. Wlnther 1
  • 1 Institut für Physikalische Chemie der Universität Köln und Abteilung Chemische Physik Institut für Physikalische Chemie der Universität Kiel


The principle of phase independent anharmonicity constants has been applied to the assignment of the infrared spectra of gaseous and liquid 1-chloro-1-cyanoethylene. The transferability of the anharmonicity constants of 1,1-dichloroethylene and some other objective criteria have also been utilized. An attempt has been made to correct for vibrational resonances and to determine the harmonic frequencies of H2C:CCl(CN).

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A Journal of Physical Sciences: Zeitschrift für Naturforschung A (ZNA) is an international scientific journal which publishes original research papers from all areas of experimental and theoretical physics. In accordance with the name of the journal, which means “Journal for Natural Sciences”, manuscripts submitted to ZNA should have a tangible connection to actual physical phenomena.