UPS Study of Spirosilane

Igor Novak 1  und Branka Kovač 2
  • 1 Department of Chemistry, National University of Singapore, Singapore 117543, Singapore
  • 2 Physical Chemistry Division, “Ruđer Boškovič” Institute, HR-10001 Zagreb, Croatia

The electronic structure of 2,7-dimethyl-5-silaspiro[4,4]nona-2,7-diene has been investigated by UV photoelectron spectroscopy (UPS). The analysis of the spectra has been performed by DFT and ROVGF calculations and comparison with the UPS spectra of related compounds. An unusual π-orbital degeneracy in this molecule of C2-symmetry was observed. The spiroconjugation is quenched, and the reasons are discussed.

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