Reaktionen von 1-Phenyl-3-alkoxycarbonyl-triazenen mit Lewis-Säuren in Benzol. / Reactions of 1-Phenyl-3-alkoxycarbonyl-triazenes with Lewis Acids in Benzene

Richard Kreher 1  and Kurt Goth 1
  • 1 Institut für Organische Chemie der Technischen Hochschule Darmstadt

1-Phenyl-3-alkoxycarbonyl-triazenes react with aluminiumchloride in benzene by elimination of nitrogen, especially to alkylbenzenes and diphenyl; anilin is formed with practical constant yield, independently of the alkyl group. On the basis of these experimental results during the reaction of alkoxycarbonyl azides with benzene under the influence of Lewis acids triazenes are not formed as intermediates

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Zeitschrift für Naturforschung B is an international scientific journal which publishes original papers, microreviews, and letters from all areas of inorganic chemistry, solid state chemistry, coordination chemistry, molecular chemistry, and organic chemistry.