Notizen: Mechanistic Implication of “LFER” in the Oxidation of Acetophenones by Vanadium(V)

M. S. Kelkar 1 , R. Shanker 1  and G. V. Baxore 1
  • 1 Chemistry Department, M. B. College Buildings, University of Udaipur, Udaipur, India

A linear combination of the effect of substituents on pre-equilibrium and subsequent rate limiting step, K and k respectively, describes the structure reactivity, relationship of the form log k/k0 = -2.17σ++ 3.3 σ, where former corresponds to V(V)-ketone complex and the latter its rate limiting disproportionation

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Zeitschrift für Naturforschung B is an international scientific journal which publishes original papers, microreviews, and letters from all areas of inorganic chemistry, solid state chemistry, coordination chemistry, molecular chemistry, and organic chemistry.