Die Kristallstruktur von Te6O11Cl2 / The Crystal Structure of Te6O11Cl2

Walter Abriel 1
  • 1 Institut für Anorganische Chemie der Universität Regensburg, Universitätsstraße 31, D-8400 Regensburg


Crystals of the title compound are monoclinic (space group P21/m) with a = 6.844(4) Å, 6 = 6.800(4) Å, c= 15.227(9) Å, y= 120.19° and Z = 2. The structure contains infinite cationic [(Te12O22) 4+]∞ -chains with three different sites for tellurium. There are three oxygen atoms in a y-tetrahedral arrangement around Te 1, and four oxygen atoms in a ψ-trigonal-bipyramidal coordination around Te 2 and Te 3.

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Zeitschrift für Naturforschung B is an international scientific journal which publishes original papers, microreviews, and letters from all areas of inorganic chemistry, solid state chemistry, coordination chemistry, molecular chemistry, and organic chemistry.