Darstellung und spektroskopische Charakterisierung der Oxorhenate(V), [ReOI4]und [ReO(SCF3)4]/ Preparation and Spectroscopic C haracterization of the Oxorhenates(V), [ReOI4]and [ReO(SCF3)4]

W. Preetz 1
  • 1 Institut für Anorganische Chemie der Christian-Albrechts-Universität, Olshausenstraße 40, D-W-2300 Kiel

By ligand exchange reactions of (n-Bu4N )[ReOBr4] with NaI dissolved in acetone pure (n-Bu4N )[ReOI4], and with AgSCF3 suspended in dichloromethane (n-Bu4N )[ReO(SCF3)4] have been prepared for the first time. The vibrational spectra of both complexes are assigned according to point group C4v, supported by normal coordinate analysis based on a general valence force field. 13C and ,19F NMR spectra provide evidence for the equivalence o f the SCF3 groups.

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Zeitschrift für Naturforschung B is an international scientific journal which publishes original papers, microreviews, and letters from all areas of inorganic chemistry, solid state chemistry, coordination chemistry, molecular chemistry, and organic chemistry.