Synthesis and Molecular Structure of [Fe2Cl2(μ-S-tBu)211-μ-dppe)] (dppe = Ph2P(CH2)2PPh2)

Han Vinh Huynh 1 , Roland Fröhlich 2  and F. Ekkehardt Hahn 1
  • 1 Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Straße 8, D-48149 Münster
  • 2 Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, D-48149 Münster

The red title compound was synthesized by the metathesis reaction of [FeCl2(dppe)] (dppe = Ph2PCH2)2PPh2) and NaS-tBu in THF. The X-ray structure analysis revealed a dinuclear complex with two iron(II) centers coordinated in a distorted tetrahedral fashion by two bridging thiolates, one bridging dppe molecule and one terminal chloro ligand.

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Zeitschrift für Naturforschung B is an international scientific journal which publishes original papers, microreviews, and letters from all areas of inorganic chemistry, solid state chemistry, coordination chemistry, molecular chemistry, and organic chemistry.